#insertion
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Irradiation at 300 nm converts the trans cinnamide side chain of structure 2 to the cis isomer of structure 3, while the reverse process occurs at 254 nm.
In this case, however, the orientation of the cis double bond prevents the side chain inserting into the cavity and so in that mode the machine is turned off. By contrast, the trans alkene moiety does allow insertion, and so in this mode the machine is turned on. (...) The photoisomerisation of the trans cinnamide side chain of structure 2 and the cis isomer of structure 3 provides the machine with an on/off switch.
"Chemistry" 2e - Blackman, A., Bottle, S., Schmid, S., Mocerino, M., Wille, U.
#book quote#chemistry#nonfiction#textbook#irradiation#trans#cinnamide#isomer#on off#double bond#alkene#moiety#insertion#nanotechnology#machine#photochemistry#uv light#ultraviolet light
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La Mode nationale, no. 50, 15 décembre 1894, Paris. no. 2. — Carré en guipure sur filet. Modèle de Mme Marchais, 46, rue de Clichy, à Paris. Bibliothèque nationale de France
Explication des gravures:
No. 2. — Carré en guipure sur filet (Modèle de Mme Marchais, 46, rue de Clichy). Après avoir fait voire carré, montez-le sur un cadre en fil de laiton ou sur un métier, a fin de bien le tendre, ce qui facilite le travail et en fait la régularité. Pour broder le filet, prenez du fil à dentelle, bien brillant, puis commencez à faire tous les contours au point de reprise, ensuite remplissez tous les motifs au point de toile.
Ce joli carré peut servir comme entre-deux de rideaux ou peut encore orner le milieu d'une tétiere, coussin, etc.
No. 2. — Square in guipure on netting (Model by Mme Marchais, 46, rue de Clichy). After making even square, mount it on a brass wire frame or on a loom, in order to stretch it well, which facilitates the work and makes it regular. To embroider the net, take very shiny lace thread, then start making all the outlines with the darning point, then fill in all the patterns with the canvas point.
This pretty square can be used as a curtain insertion or can even adorn the middle of a headrest, cushion, etc.
#La Mode nationale#19th century#1800s#1890s#1894#periodical#fashion#pattern#lace#guipure#chart#Marchais#Bibliothèque nationale de France#insertion#entre-deux
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sometimes i can’t think of literally anything other than the first feeling of sliding in her. it’s my favorite place to be.
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my size kink ass, who can barely fit my small size BD, just came hard as fuck trying to fit my wand vibe inside bc that is 😅 certainly a kink of mine
#it didnt fit and im sore. the stretch burrned but it was good#like such a burn i was worried my wand was getting hot but any time i passed it over my dick it wasn't and i was like.#oh. that's what they mean by burning stretch.#my post#size kink#insertion#stretching
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Me and who
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I was inspired
#gravity falls#book of bill#ford pines#stanford pines#bill cipher#dipper pines#Mason pines#billford#I guess you could call him my muse heh *inserts that one tiktok smug emoji*#no ford is not referring to twink bill it’s literally just triangle bill#the family reunion is gonna be a lot more awkward now
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•Normalize Fanart for Fanfics Again You Fools•
It's not cringe anymore (it SHOULDN'T be cringe anymore), just do it. You're doing something you enjoy, who cares what anybody else says! So spread the words my fellow internet brethren.
Spread the Word :)
#fanfic#fanfiction#fanart#normalizefanartforfanfics#normalize fanart for fanfics#wattpad#archive of our own#ao3#fanfiction.net#quotev#crossover#crossovers#fandom#fandoms#readerinsert#reader insert#xreader#x reader#oc#oc's#au#alternate universe#podfic#fic rec#fanart for fanfic#fanartforfanfic#fanart for others#fan fiction#fan fic writing#fanfic fanart
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Bitches will find a fictional man attractive and then immediately imagine him in situations where he is losing alarming amounts of blood
#its me im bitches#malevolent#arthur lester#ofmd#fionna and cake#simon petrikov#you knowwww#insert fandom here kinda vibes
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Is this anything
#always an awkward conversation to have irl#“i love ai.” insert that one spongebob holding out his hands with a shadow above him meme#“FICTIONAL. FICTIONAL AI!!!”#clankerposting#Clay posts#fictional ai#shitpost#hal 9000#robots#p03#electric dreams#allied mastercomputer#ihnmaims#shockwave#transformers#fuck ai#this is an anti ai art blog btw#objectum#saying hello to everyone who reads the tags um... hi!! Really funny to read people recommending me entry level robot/AI media#like yes i have indeed heard of portal and ultrakill. i just didnt pit them in the meme </3#also some guy decided to write in the notes that they were going to crush me into red paste. hot? thank you? ???? weird.
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me logging onto tumblr after consuming a new piece of media
#me core after watching deadpool and wolverine#joel miller x reader#peter parker imagine#matt murdock x reader#peter parker x reader#steve rodgers x reader#bucky barns x reader#logan howlett x reader#carmen berzatto x reader#james potter x reader#remus lupin x reader#sirius black x reader#regulus black x reader#tangerine x reader#aaron hotchner x reader#spencer reid x reader#wade wilson x reader#rafe cameron x reader#x reader#reader insert#mike schimdt x reader#ethan landry x reader#marcus acacius x reader#jj maybank x reader
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CASSARINA Silicone Automatic Bookmarks with Pen Insertion, Cute Book Marks Gifts for Reading Women, Men, Kids, Book Lovers, Readers, Unique Book Page Holders & Accessories (Multicolor) (Pack of 3)
Price: (as of – Details) ✔automatic bookmarks, book accessories, silicone book markers, gifts for reading book lovers.✔ favored by children Simple and not lacking in delicate bookmarks Change the inherent shape of traditional bookmarks With a novel shape as the element.✔ the duckbill clip is designed to be easy to install, easy to open and close, and can be recycled.✔ The innovative design makes…
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#Accessories#Automatic#book#book markers for novels#Bookmarks#CASSARINA#Cute#Gifts#Holders#Insertion#Kids#lovers#Marks#Men#Multicolor#Pack#PAGE#Pen#Readers#Reading#Silicone#Unique#Women
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not to sound like a boomer, but I need some people to learn how to write emails in a semi-professional (at the very least) format so you're not cold emailing a business/potential employer/any other stranger about formal matters in the exact same way you'd DM a close friend on instagram
the formality/language can loosen up in the email chain once you've established a rapport and you match the other person if they're being less formal, but please don't have the very first email you send a stranger be written in all lowercase ultra-casual sms slang with no greeting or signature and a billion emojis
#this sounds like a 'argh kids these days doing [insert exaggerated story they don't actually do in reality]' kind of thing#except that I've gotten soooo many emails like this#there's a reason that I don't have my DMs open on any socmed and it's bc they attract people getting way too casual/parasocial immediately#and forcing people to write out an email both filters out 90% of weird impulse messages and also throws them out of that casual headspace#except that I can actively tell when this fails and someone is treating emails as if they're the same thing as DMs
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sea grunks bonding because I feel like the universe needs more of it
#also inserting my headcanons for their sexualities because I can#gravity falls#gravity falls comic#sea grunks#stan and ford#stanley pines#stanford pines
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