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I was quick to smell my thumb, my right thumb (I asked the woman with the special ink if it had to be the left or right one; she said any would work); and a repugnant and strong smell of acetic acid filled my inner flesh tubes which made me let out a quite audible disgust reflex.
I had just voted in my first election for this nation; and after that my family and I went to the mall. Despite how many mentioned was the fact that so many stores would give free stuff after you showed them your inked thumb; I went to none of them, I wasn't really excited for such.
I wasn't excited for voting in the first place. Me like many people have lost all their faith in the whole process, I had planned since the last year that I would straight up cast an invalid/blank vote, and the whole campaign process that came after just reassured me on such choice.
So if I was going to do that, at least I should make something out of it.
And that's how the name of "Boxa Caken Funfetti" written with the black crayon that is given at the voting place, marked the first ever recorded case of a Sparklecare character being voted as a candidate in a presidential election.
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acetic acid
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it's fun to open up Ms paint and doodle a thing
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As part of this effort, the Molecular Design and Synthesis Group at the University of New South Wales has been designing tagging agents that will temporarily introduce highly fluorinated alkyl groups to molecules to aid in organic synthesis (for example, see figure 18.17).
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"Chemistry" 2e - Blackman, A., Bottle, S., Schmid, S., Mocerino, M., Wille, U.
#book quotes#chemistry#nonfiction#textbook#research#molecular design and synthesis#university of new south wales#unsw#fluorination#alkyl group#organic chemistry#diol#polyfluoroalkyl#chemical reactions#acetic acid#oxidation
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Vinegar could be secret ingredient in fight against climate crisis
Chemical engineers at Monash University have developed an industrial process to produce acetic acid that uses the excess carbon dioxide (CO2) in the atmosphere and has a potential to create negative carbon emissions.
Acetic acid is an important chemical used in several industrial processes and is an ingredient in household vinegar, vinyl paints and some glues. Worldwide industrial demand for acetic acid is estimated to be 6.5 million tons per year.
This world-first research, published in Nature Communications, shows that acetic acid can be made from captured CO2 using an economical solid catalyst to replace the liquid rhodium or iridium based catalysts currently used.
Liquid catalysts require additional separation and purification processes. Using a solid catalyst made from a production method that doesn't require further processing also reduces emissions.
Read more.
#Materials Science#Science#Vinegar#Acetic acid#Reactions#Carbon dioxide capture#Catalysts#Liquids#Metal organic framework#Monash University
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Aspirin is synthesised on an industrial scale by reacting acetic anhydride with salicylic acid:
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"Chemistry" 2e - Blackman, A., Bottle, S., Schmid, S., Mocerino, M., Wille, U.
#book quote#chemistry#nonfiction#textbook#aspirin#synthesis#chemical reactions#acetic anhydride#salicylic acid#hydroxybenzoic acid#acetylsalicylic acid#acetic acid
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My knowledge in microbiology and biology informs my decisions
#Knowing how extensive#mold#is#and what#snails#carry#nooooo thanks#also I just hate the smell#texture and taste of overripe food#that#acetic acid#butyric acid#food#food disgust
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Acetic Acid Prices, News, Trend, Graph, Chart, Monitor and Forecast
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Acetic Acid is a vital chemical compound used across a variety of industries, including the production of chemicals, food, textiles, and pharmaceuticals. It is primarily used as a solvent, reagent, and intermediate in the synthesis of other chemicals such as acetate esters, acetic anhydride, and vinyl acetate monomer. The market for acetic acid is vast and dynamic, influenced by various factors, including supply and demand dynamics, raw material prices, technological advancements, and environmental regulations. Acetic acid prices have been subject to fluctuations over the years due to changes in production costs, geopolitical factors, and shifting market trends.
The production of acetic acid is primarily driven by two processes: the carbonylation of methanol and the oxidation of hydrocarbons. Methanol-based production is the most common method, accounting for a significant share of global acetic acid production. The demand for acetic acid is largely influenced by industries that rely on its derivatives, such as the manufacturing of synthetic fibers, plastics, and food additives. The pharmaceutical and cosmetic industries also contribute to the demand for acetic acid, as it is used in the formulation of various products such as ointments and preservatives.
Get Real time Prices for Acetic Acid: https://www.chemanalyst.com/Pricing-data/acetic-acid-9
In recent years, acetic acid prices have experienced some volatility, driven by factors such as fluctuations in feedstock prices, changes in production capacity, and shifts in regional demand. One of the primary factors impacting acetic acid prices is the cost of raw materials, particularly methanol, which is the main feedstock in acetic acid production. The price of methanol has been known to fluctuate due to changes in global oil prices, as methanol is often derived from natural gas or coal. As a result, when methanol prices rise, acetic acid production costs increase, putting upward pressure on the price of acetic acid.
Another key factor that influences acetic acid prices is the level of global supply and demand. When there is an oversupply of acetic acid in the market, prices tend to decrease as producers compete to sell their products. Conversely, when supply is limited, prices rise as demand outpaces production. Regional factors play a significant role in determining the supply-demand balance, with key markets such as China, the United States, and Europe being major players in the acetic acid industry. For instance, China is both the largest producer and consumer of acetic acid globally, and any shifts in the country’s demand or production capacity can have a substantial impact on prices. Similarly, economic growth or slowdowns in key regions can also influence acetic acid demand, impacting pricing trends.
Environmental regulations are another factor influencing acetic acid prices. Governments around the world are increasingly focused on reducing carbon emissions and promoting more sustainable production practices. This has led to the implementation of stricter regulations on industries involved in the production of chemicals like acetic acid. These regulations often require companies to invest in more advanced technologies or to adopt cleaner production methods, which can increase production costs and, in turn, lead to higher acetic acid prices. On the other hand, the growing focus on sustainability has also led to innovations in acetic acid production processes, with some companies seeking to develop more energy-efficient or environmentally friendly methods. These advancements may help mitigate cost pressures in the long term.
Technological advancements and process improvements in acetic acid production have also played a role in shaping price trends. Over the years, significant efforts have been made to improve the efficiency of acetic acid production, reduce energy consumption, and lower production costs. For instance, advancements in catalysts and reaction systems have allowed for the more efficient conversion of methanol to acetic acid, reducing the amount of energy required and increasing overall yield. These innovations can help to keep acetic acid prices more stable, particularly when raw material prices are volatile. Additionally, the development of new production methods, such as the use of renewable feedstocks, may provide an opportunity to reduce the reliance on fossil fuels, potentially lowering production costs in the future.
The acetic acid market is also influenced by the global economic environment. When the global economy experiences growth, industrial production typically rises, leading to increased demand for acetic acid and its derivatives. For example, during periods of economic expansion, demand for consumer goods, automotive products, and construction materials tends to increase, driving up the need for acetic acid in the production of plastics, paints, and coatings. However, during economic downturns or periods of recession, industrial activity slows, and demand for acetic acid often declines, leading to downward pressure on prices.
In addition to economic factors, geopolitical issues can also impact acetic acid prices. Trade disputes, tariffs, and political instability in key producing or consuming regions can disrupt the supply chain, leading to price fluctuations. For instance, a trade dispute between major acetic acid-producing countries could lead to supply shortages or disruptions, causing prices to rise. Similarly, political instability in key regions, such as the Middle East, can affect the global supply of oil and natural gas, which are key feedstocks for methanol production, thereby impacting the cost of acetic acid.
The competitive landscape in the acetic acid market also affects pricing trends. The market is characterized by the presence of several large multinational chemical companies, as well as smaller regional producers. Intense competition among producers can sometimes lead to price wars, where companies reduce prices to gain market share. However, in times of supply shortages or rising raw material costs, producers may raise prices to offset the increased costs of production. Pricing strategies vary across regions, and producers often adjust their pricing based on local market conditions, production capacities, and demand fluctuations.
In conclusion, the acetic acid market is a complex and multifaceted industry that is influenced by a range of factors, including raw material prices, supply and demand dynamics, environmental regulations, and technological advancements. Price fluctuations in acetic acid are inevitable due to the interconnected nature of the global economy and supply chains. While the industry is expected to continue experiencing price volatility, ongoing innovations in production processes and the adoption of more sustainable practices may help stabilize prices over time. Understanding these factors and monitoring market trends is essential for businesses and consumers to navigate the ever-changing landscape of acetic acid pricing.
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#Acetic Acid#Acetic Acid Price#Acetic Acid Prices#India#united kingdom#united states#Germany#business#research#chemicals#Technology#Market Research#Canada#Japan#China
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Toxicity ADI is not restricted (FAO/WHO, 2001). LD504.96g/kg (mouse, oral). GRAS (FDA, §184.1005, 2000). Usage limit GB2760-96: Compound seasoning, canned food, prepared vinegar, cheese, jelly, limited by GMP. Acetic acid is also a permitted edible flavoring. FAO/WHO (1984): Tomato, asparagus, baby food, sardine, mackerel, bream and other canned food, pickles, broth, cold drinks, acid casein, caseinate, etc. are subject to GMP; processed cheese 40mg/kg; edible fungi or fungal products are subject to GMP, but pickled fungi 20g/kg. FEMA (mg/h): soft drinks 39; cold drinks 32; candy 52; baked goods 38; puddings 15; gum candy 60; condiments 5900. FDA (§184.1005, 2000): 0.25% for baked goods; 0.8% for cheese and dairy products; 0.5% for gum, oils and fats; 9.0% for condiments; 0.3% for white wine and sauces; 0.6% for meat products; 0.15% for other foods. Maximum allowable use of food additives Maximum allowable residue standard ▼▲ Chinese Acetic acid name of additive Chinese name of food in which this additive is allowed to be used Function of additive Maximum allowable use (g/kg) Maximum allowable residue (g/kg) Acetic acid Food Food spices Each spice ingredient used to prepare flavors shall not exceed the maximum allowable use and maximum allowable residue in GB2760 Acetic acid Food acidity regulator Use in appropriate amount according to production needs (except for special provisions) Chemical properties Colorless transparent liquid with pungent odor. Miscible with water, ethanol, benzene and ether, insoluble in carbon disulfide.
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The Science Diaries of S. Sunkavally, page 339.
#fulminic acid#precipitation#needles#scales#acetic acid#solvent#oils#ascorbic acid synthesis#humans#subcutaneous fat#pregnancy#fever#birth defects#cytokines#leukotrienes#clostridium tetanii#tetanus#rabies#gold oxide#gold chloride#gold hydroxide#formaldehyde#B-hydroxybutyrate#starvation#trance#satyendra sunkavally#theoretical biology#cursive handwriting#manuscript#notebooks
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Hollow Cut Hair Accessories
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#ice#float#water#hydrogen bond#lewis acidity#amines#acetic acid#formic acid#benzene#chemistry#solutions
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Figure 11.7 shows the different conductivities of aqueous solutions containing HCl and CH3COOH.
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"Chemistry" 2e - Blackman, A., Bottle, S., Schmid, S., Mocerino, M., Wille, U.
#book quotes#chemistry#nonfiction#textbook#hydrochloric acid#acetic acid#conductivity#electrical conductivity#aqueous solution
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From Vinegar to Versatility: Unveiling Acetic Acid's Production Journey and Multifaceted Applications
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Vinegar. That pantry staple we splash on salads and fries. But did you know this common household item packs a surprising scientific punch? The key ingredient in vinegar is Acetic Acid, a clear, colorless liquid with a powerful odor that's sure to clear your sinuses. Acetic Acid is much more than just a souring agent. It's a workhorse in the chemical world, playing a crucial role in the production of countless everyday items. From the plastics in your water bottle to the medicines in your cabinet, Acetic Acid might be lurking behind the scenes.
In this blog, we'll delve deeper into the fascinating world of Acetic Acid. We'll explore its surprising range of uses, from the industrial to the culinary, and uncover the science behind its unique properties. So, whether you're a curious cook or a science enthusiast, get ready to learn a whole new side to the humble vinegar you know and love!
Introduction
Acetic Acid, a clear organic compound with a strong odor and tart flavor, is industrially synthesized through methanol carbonylation or ethylene oxidation. Methanol carbonylation is the preferred method over ethylene oxidation. Key technology providers for Acetic Acid production include British Petroleum, Celanese, Eastman's acetyls technology, and LyondellBasell. Similar to ethanol, Acetic Acid is a water-friendly solvent, readily mixing with water, chloroform, and hexane, and dissolving substances such as oils, sulfur, and iodine.
It serves as a chemical precursor for various compounds like acetic anhydride, esters, vinyl acetate monomer (VAM), and various polymers. Acetic Acid is also utilized in vinegar production, where it constitutes 5 percent of the solution, finding applications in the food and beverage industry for marinades, pickling solutions, and salad dressings. Additionally, vinegar, containing Acetic Acid, can be added during food preparation to minimize contamination in meat and poultry products.
Manufacturing Process
Acetic Acid primarily undergoes production through chemical methods, utilizing both homogeneous and heterogeneous catalytic processes. The predominant method involves the carbonylation of methanol, a process initially established by Monsanto, which has since progressed into the Cavita process. This evolved approach offers flexibility in catalyst selection and incorporates advancements in process intensification techniques.
Methanol carbonylation process:
• The carbonylation process, commonly referred to as the Monsanto process, stands as the predominant commercial method for synthesizing Acetic Acid.
• Methanol and carbon monoxide undergo a liquid-phase reaction under the influence of a rhodium (Rh)-based catalyst at temperatures ranging between 150 to 200 degrees Celsius and pressures between 30 to 50 bar, yielding Acetic Acid with a selectivity of around 95% and minor side products including formic acid and formaldehyde.
• In this process, hydrogen iodide serves as an alkali promoter, with the reaction occurring in the liquid phase and methyl acetate acting as a solvent using a homogeneous catalyst. The controlled introduction of water is necessary for the reaction, which is generated in situ through the reaction of methanol��with hydrogen iodide.
• The reaction rate in the Monsanto process is directly influenced by the concentration of water. Byproducts such as CO2, H2, and methanol are generated during the reaction, with the produced methanol being recycled. Over time, the process has undergone evolution, with various strategies implemented to separate pure Acetic Acid from a mixture of water and byproducts. BP Chemicals modified this process by substituting the rhodium-based catalyst with an Iridium (Ir) catalyst, resulting in what is known as the Cavita process.
• The selection of Ir as a coordination metal presents a relatively more economical approach compared to rhodium. The use of an iridium catalyst enhances the overall reaction rate.
The following chemical reaction represents the same:
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Acetaldehyde oxidation process
• The acetaldehyde oxidation method was one of the largely used method used for synthesizing Acetic Acid. Initially, acetaldehyde was prepared through the oxidation of ethylene, employing palladium and copper chloride catalysts, after which it underwent further oxidation to yield Acetic Acid.
• Alternatively, a similar procedure utilizing cobalt and chromium-based catalysts has been documented, operating at a pressure of 55 bar and a temperature of 150 degrees Celsius. Another variant of this process involves a one-step conversion of ethylene to Acetic Acid, employing lead and lead-platinum based catalysts at elevated pressures, in contrast to the acetaldehyde oxidation method, albeit with lower Acetic Acid yields.
Hydrocarbon oxidation process
• Petroleum-derived hydrocarbons, including butane and naphtha, serve as the primary sources for producing Acetic Acid, a crucial chemical compound, through a reaction catalyzed by cobalt acetate and chromium acetate.
• This chemical transformation unfolds within a relatively elevated temperature range of 150-230°C and under pressures ranging from 50 to 60 bar. The utilization of petroleum feedstock, comprising a diverse hydrocarbon blend, initiates a multifaceted reaction pathway leading to the synthesis of not only Acetic Acid but also a spectrum of byproducts, notably acetone, formic acid, and propionic acid, alongside the target compound. Consequently, the resultant Acetic Acid may not exhibit a high degree of purity due to the coexistence of these impurities.
• However, this process's strength lies in its capability to generate a mixture of volatile fatty acids, rendering it more suitable for applications necessitating such a blend. Therefore, while it may not yield pristine Acetic Acid, this method finds relevance in industrial contexts where a mixture of volatile fatty acids is desirable. This underscores the importance of understanding the nuanced outcomes of chemical processes and tailoring them to meet specific industrial requirements.
Applications of Acetic Acid
1. Food & Beverages
Acetic Acid finds its primary application in the culinary sector, predominantly in the form of vinegar. Throughout history, it has served as a condiment, flavor enhancer, and preservative in pickling. Vinegar remains integral in various processed foods, including mayonnaise, due to its typical sour flavor and preserving properties. Acetic Acid finds application in preserving and pickling various food items such as vegetables and fruits, effectively thwarting spoilage and prolonging their shelf life. Its presence contributes to the characteristic tanginess observed in pickled foods.
2. Chemical Intermediates
Acetic Acid serves as a vital chemical reagent in the synthesis of various compounds. Its primary application lies in the production of vinyl acetate monomer, followed closely by acetic anhydride and ester production. While Acetic Acid is commonly associated with vinegar, its usage volume in this context is relatively minor compared to its extensive utilization in industrial processes for the production of essential chemical compounds. Acetic Acid serves as a foundational component in the production of various chemicals, including vinyl acetate, acetic anhydride, and acetate esters. Vinyl acetate is utilized in the synthesis of polyvinyl acetate, a versatile polymer applied in paints, adhesives, plastics, and textile finishes. Acetic anhydride finds application in the manufacturing of cellulose acetate fibers and plastics used in photographic film, clothing, and coatings. Furthermore, Acetic Acid plays a crucial role in the chemical process to produce purified terephthalic acid (PTA), essential for manufacturing PET plastic resin. PET resin is extensively employed in synthetic fibers, food containers, beverage bottles, and plastic films.
3. Cosmetics
Acetic Acid is a common component in many cosmetic items. It serves as an ingredient in hair conditioners, shampoos, and various other hair care products. Additionally, derivatives of Acetic Acid, such as alkyl acetates and acetate salts, contribute to the formulation of perfumes and skin conditioners. These derivatives play crucial roles in enhancing the effectiveness and sensory characteristics of cosmetic formulations, ensuring optimal performance and user satisfaction across a range of personal care applications.
4. Household Cleaners
Due to its acidic nature, Acetic Acid serves as a potent cleaning agent and disinfectant, commonly employed for sanitizing windows, countertops, and various surfaces in both residential and industrial environments. It presents a natural substitute for harsher chemicals and is particularly adept at removing limescale buildup in appliances like kettles and coffee makers. Its versatility extends to diverse cleaning tasks, offering an effective and eco-friendly solution for maintaining cleanliness and hygiene.
Market Outlook
The Acetic Acid market is influenced by the combination of industrial, economic, and regulatory factors. The main factors that drive the demand are the growing need in different industries like textiles, packaging, automotive, and construction, where Acetic Acid is a key component in the production of vinyl acetate monomer (VAM), purified terephthalic acid (PTA), acetate esters, and solvents. Besides, the chemical industry, which is growing especially in the developing countries such as China and India, is one of the factors that leads to the increase of the demand for Acetic Acid since it is a basic material for the production of many chemicals. Besides, the increase in the adhesive and sealant industry, caused by the rising construction activities and the demand for consumer goods, also brings the Acetic Acid demand up. The fast urbanization and the infrastructure development projects across the globe also are the reason behind the growth of the market, as Acetic Acid is a necessary component of the construction materials like paints, coatings, and adhesives.
Acetic Acid Major Global Players
Major players in the Global Acetic Acid market are Celanese Corporation, Eastman Chemical Company, LyondellBasell Industries N.V., Yangtze River Acetyls Co. Ltd (YARACO), The Saudi International Petrochemical Company (Sipchem), INEOS PCG ACETYLS SDN BHD (IPASB), Lotte BP Chemical, Gujarat Narmada Valley Fertilizer and Chemicals, Formosa BP Chemicals Corporation, British Petroleum, Formosa BP Chemicals Corporation, Formosa INEOS Chemicals Corporation (FBPCC), EuroChem Group AG, and Others.
Conclusion:
To sum up, the Acetic Acid market is set to keep on growing and changing due to a wide range of factors such as industrial demand, regulatory shifts and technological advancements. Acetic Acid is a very important chemical which has many applications in all the industries such as textiles, automotive, construction, and so on. Thus, it is the essential chemical for the processes and products. The growing chemical industry, especially in the developing economies, is the evidence of the growing demand of Acetic Acid as a basic chemical in chemical synthesis. Besides, the increasing of adhesive and sealant industry, the rapid urbanization and infrastructure development of the world and the need for Acetic Acid in the construction materials and consumer goods are also the reasons for the growth of the demand for Acetic Acid. Besides, the industry's transformation to the bio-based production methods and sustainability initiatives is proof of the shift towards the more eco-friendly practices. The market will keep on changing; hence it is important for the stakeholders to be up to date with these trends and developments so that they can take advantage of the emerging opportunities and at the same time avoid the possible problems. In a nutshell, the Acetic Acid market is expected to be a great one in the future, due to the innovation, diversification of demand, and sustainability imperatives.
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Common solvents for these reactions are divided into two groups: protic and aprotic.
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"Chemistry" 2e - Blackman, A., Bottle, S., Schmid, S., Mocerino, M., Wille, U.
#book quote#chemistry#nonfiction#textbook#solvent#protic#aprotic#water#formic acid#methanol#ethanol#acetic acid#dimethyl sulfoxide#dmso#acetone#dichloromethane#diethyl ether
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