#TPN 102 | Explore Tumblr posts and blogs

fullscoreshenanigans · 7 months ago

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hi sorry feel free to ignore this, do you know if there are any fics out there that focus on ray's memory?? idk if he has an eidetic memory or just lacks infantile amnesia, but either way would be cool if there was a fic about it somewhere out there

You could make a case for him having eidetic memory with instances like these:

(Chapter 100 | Chapter 102)

But Shirai never confirmed it one way or the other, so one is free to take it as far as they want with their headcanons.

As for fanfics, do you mean where the narrative is shaped around his memory as the focal point or as a substantial part of the backdrop that informs his character?

I can't recall anything that would fall into the former, but for the latter I think of SuddenWhispers/withlovehaven's Tethered

and @hylialeia's hoping you're someone i used to know.

Repeating myself from this post where I recommended them before, but it's always a treat when you find fics like these. Delivered in gorgeous lyrical cadence, such loving attention is paid to sentence composition that the words aren't merely a means to an end, but a reflection of a deep appreciation for both these characters and the craft itself, the weight of them meant to be lingered over and savored. Among my gold standard for TPN fanfic, and canon in my heart. <3

[Other FSS fanfic recs found here, here, here, here, and here]

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fullscoreshenanigans · 1 year ago

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Reading these popularity polls and feeling like I'm going lowkey insane

(WSJ Chapter 102 Popularity Poll, released September 7, 2018)

(Official Anime Site's 4th Anniversary Popularity Poll, conducted in August 2020)

(VIZ February 2021 Popularity Poll)

Anna being more popular in fanon that Don illustrates the phenomon of a fandom being willing to do one of their least favorite things (appreciate a female character) in order to avoid doing another one of their least favorite things (appreciate a character of color)

#Eurocentric beauty standards and cishet ship brainrot is a hellavu drug combo #Ch102 poll is especially crazy because her big moment in the spotlight in Ch116-117 #where she goes to help get the medicine for Chris didn't happen yet where you can maybe justify it as something else #but like. You're delusional if you don't think a significant portion of that popularity comes from her being #a conventionally cute‚ blonde-haired‚ blue-eyed white girl with how much more consistently involved Don (and Gilda) are in the story #Phil outranking so many characters in relation to his role is also a thing #but he did have that major defining character moment where he took on the burden of the secret at the tender age of 4 #during one of the greatest emotional climaxes of the series that even people who say the series fell off remember fondly #and that poll coming out two chapters after he showed up again in the story during Ch100 #on top of being a cute bby #so while he isn't ranked as my 4th favorite character it's way more understandable to me than Anna's placement #also something something using this as a way to neutralize Ray as a “threat” to NE #by pairing him off with the conventionally cute blonde girl when he's had more consistent interactions with Don and Gilda #my personal red flag for a ship line-up if only because it's frequently done in the most bland comphet way possible #with RA and GD being used primarily to prop up NE as opposed to more genuine interest in the ships on their own #TPN References #TPN Polls #Fandom Salt #TPN Salt #Fandom Wank #TPN Cast #Grace Field Kids #Anna #Don #TPN S1 #Cuvitidala Arc #TPN 102 #Seven Walls Arc #TPN 131

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autisticempathydaemon · 1 year ago

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Take all the time you need hun! I don’t wanna make you feel rushed or anything, life is always busy 💞💞💞

What song are you fixated on at the moment? What lyric or verse, and why?

Both Over & Over by Rio Romeo and Again&Again by The Bird and the Bee, those two songs have been stuck in my head recently, it fits this fear I have in my mind that I’m never truly growing or I’m never actually gonna leave where I am, that I’ll always fall victim to habit and paranoia 💃🏽 also I just ADORE my meloncholy depressing songs lol but that’s not very heehee haha of me soooo Spider Web by Melanie Martinez bc it has the sound of a Coqui in it (I’m Puerto Rican) or River is a Vampire by Bear Ghost and Dan ET bc it’s just the vampiric version of that one meme “How you do my fellow kids” and it kills me

• What is your Enneagram type?

I think I’m a type 4? but I do know I’m an ENFP!

• Do you love gargantuan Youtube video essays, and if so, which is your favorite and why?

God I haven’t watched a video essay in AGES but I used to love them, but idk what gargantuan is </3 but I typically like video essays about internet history or crime cases, or of shows I enjoy (like MLP)

• Tell me about your childhood imaginary friend.

SHE WAS A CHEETAH WHO WAS ALWAYS THERE FOR ME NO MATTER WHAT!!! I would pet her, talk to her, and she’d keep me company when everyone would isolate me/avoid me bc I was ‘too weird’. She was just a big ass cat that would keep me company and run by the cars side to make sure I and my family was safe. She protected me 💞 (thank you for making me remember her 🥹)

• What is your go-to way to fall asleep?

Getting on call with my partner, I’m rather clingy and just wanna spend time with them even if it’s just silence or sleepy rambling, it also keeps me from doom scrolling. If not on call with them I’ll put on RSlash or Gavin’s/Davids sleep aid and hope that knocks me out (and if not that a ba LMFAO-) also if I have Lavender, I put it under/rub it all over my pillow and plushies

• If you had to change your name, what would it be, and why? (In tandem, if you have changed your name, why did you pick that one?)

Im genderfluid/gendervoid so I’ve tried many names, I do like my birth name, it means Loyal Protector/Pledge, so I wanted to find names that mean loyalty or music related names, but one name I’ve been using recently is Quincy, it feels nice sometimes, my partner suggested it to me.

• What is your favorite of Redacted's audios, and why?

Sam’s cuddles and confessions, it’s nice and comforting. That or Cataclysm in general, I fucking LOVE Cataclysm, I love relistening to it. Also any audio that involves Caelum I love that boy dearly

• What Redacted boy holds no appeal to you, and why? Like, not the one you hate but the one who you don't get the hype for. (I won't judge, I promise.)

Aaron and Vincent. Despite me being a huge vampire lover, Vincent just did not catch my attention at all, Aaron just doesn’t peak my fancy aside from one of his BA’s. Also same thing for Porter, he kinda bores me 😔

• Tell me about that one book/movie/tv show you know all the words to.

When I was a little kid, it was the live action 102 Dalmatians, I KNEW THAT MOVIE LIKE THE BACK OF MY HAND!!! I FUCKING LOVED WATCHING CRUELLA BEING BAKED INTO A CAKE BY ALL THOSE DOGS. Also Oddball my beloved 💞💞💞 the sweet baby puppy, I just understood the pup for feeling like and odd one out as a grew up, I haven’t seen the movie in years now but it still holds such a special place in my heart. Now as an adult my two favorite shows are The Promised Neverland(only season 1, I’m reading the manga) and Madoka Magica. I love rewatching TPN, but Madoka I have to mentally prepare myself for cause good lord does it make me feel like I never took anti-depressants/pos and then a movie I love now, A Silent Voice. I think I do know that one scene for scene. As a kid who grew up being bullied for being different or just not doing things right, I felt strongly for the main characters. I’ve cried almost every single time I’ve watched the movie. The part where one of the characters jumped off the balcony kills me every time because it reminds me how that could’ve been me from the fresh ages of 9-16 and almost was. It just holds a special spot in my heart and helps me keep going. (I adore my sad heart wrenching shit lmfao)

• Which Redacted boy are you platonically attracted to? Like- forget dating, which dude do you want to be your best friend?

Asher and Guy, those two would be so much fun to be friends with, also with the fact I’m so similar to them, especially Asher, bro is just like me fr 💀💀💀 collars and all. Like I just wanna be that man’s friend he is so silly

• Do you have a go-to thing you ramble about when you're tired, and if so, what is it? (For example, my boyfriend knows I'm ready to sleep when | start talking about space.)

As cheesy as it is, the fact I just want everyone in the world to be okay and happy, I want us all to hold hands, hug, and not hurt. I cry during these rambles sometimes, I genuinely just want everyone to be safe and happy and it tears me up inside and out bc that’s just not possible with the world we live in. That or I just start rambling nonsense lmfao (bonus is if I start rambling about how much I love and care about the person I’m talking to)

• Tell me your go-to gas station and drink combo.

Root beer and either Hot Cheetos/Cheesy Ruffles, or spicy chicken cheese sticks, meow I’m eating the shit out of that. (But if we have the money for it, Icys specifically cherry cause it’s objectively the best flavor next to Pinacolada)

• Tell me about your favorite playlist at the moment.

Like music playlist? Currently my fave has to be either my Alexis, Quinn, or my Darlin and Quinn playlists, I love my evil people playlists and songs that represent fucked up mindsets and relationships. That or my Melancholy Comfort playlist, I enjoy my meloncholy songs.

Redacted playlist tho? Either Sam, Vega, or Caelum, Sam holds a very special place in my heart, he’s incredibly comforting and ngl I miss the less sexual audios from his earlier era. Vega just drives me feral with every new piece of info we learn, GOD I FUCKING LOVE THAT ANCIENT MAN AND THE LORE HE DROPS!!! And then Caelum’s playlist holds a special place in my heart since that was the only playlist I could listen to after finding out I was cheated on/the other woman. Helped me out a lot for about 2 months 💞

• What's your guilty pleasure media, and why?

Those shitty werewolf romance things you see on tiktok, GOD I get so fucking invested in those they’re so needlessly interesting LMFAO idc they’re cringe, I’m cringe too stfu

• And whatever else you think tells me about who you are!

I’m a huge performer! I love singing, dancing, acting, especially singing and dancing. I LIVE for the stage and positive attention, I just wanna make people smile or make people feel scene when I preform. Hopefully one day I can be famous and truly fulfill that dream of mine. I also feel emotions strongly and spent my entire childhood from middle school and up studying psychology and human behavior. Also I absolutely HATE fake people, I can’t stand when people are fake, I try to be a safe person for everyone to truly be themselves cause lord knows I always hated having to put on a mask growing up/being isolated because I didn’t fit in lmfao.

I forgot to click on anon sorry-

I adore this entry- not only did you give me so much information to work with but you’ve given me an opportunity to pair you with Lasko which I love to do.

He’s such a character in need of love, and I think you’re a perfect person to love him and be loved in return for so many reasons. He’d be an introvert to your extrovert which is always an adorable couple dynamic. You’ve mentioned a past characterized by isolation and feeling other; Lasko is uniquely situated to understand and empathize with that. You prefer true, genuine people, and Lasko is so incredibly (albeit apologetically) himself and probably incapable of being anything else.

One of the most fun activities I think you and Lasko would do together is watch anime. I like to think he’s already a fan, mostly of adventure and isekai, with some cheesy shoujo faves he’s so bashful about liking. You show him A Silent Voice, which isn’t his usual genre, and you two cry together. Another fun thing is how you’ll perform and Lasko will be in the front row every time, cheering you on. He brings you a mismatched bouquet and rambles about how he couldn’t pick a dozen of one flower, so he got a little of them all.

Song:

Cause lately it's been hard/ They're sellin' me for parts/ And I don't wanna be modern art/ But I only got half a heart to give to you/ How can you miss someone you've never seen?/ Oh, tell me, are your eyes brown, blue, or green?/ And do you like it with sugar and cream?/ Or do you take it straight, oh, just like me?

You like melancholy songs; I can provide. This is one of my favorite pining songs, and it makes me think of a young Lasko (and maybe a young you) longing for connection, love, understanding, that one person who will make the love songs finally make sense. It makes me picture Lasko just waiting for you, you know?

Runner-ups:

On the total opposite of the pairing spectrum, Hudson is one of your runner-ups because he’d be such a good match to you as a performer. I personally can’t imagine a better hype man than Hudson. I’m also picking David as a runner-up for you, because I think you two would contrast each other really cutely, in a maybe golden retriever/german shepherd way.

Read this post and send me an ask if you’d like a match-up of your own! 💌

#redactedasmr #redactedverse #redacted asmr #redactedaudio #redacted audio #redacted #busybee matches

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chidoroki · 2 years ago

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182 Days of TPN - Day 102

Chapter 102: “Found It”

I don’t remember much of the demon town scenes in the anime (because honestly, who would want to remember?), but I am kinda upset we didn’t see much of these demon kids, especially the smaller one with the fascination for leaves. It’s cute.

This is some very unfortunate foreshadowing. “Yet” might as well be very large and in bold print.

If it wasn’t for the artbook, I would’ve never realized that Dominic was actually wearing an animal pelt in this panel. He has every right to be proud of it! I am too and I love this child immensely!

The way the younger kids rush to carry out Ray’s very specific request with no questions asked.. GF kids are definitely something to be feared. I would’ve definitely needed him to repeat his instructions at least thrice. Not to mention that Ray knows exactly which books he needs and where they were located. Yeah his great memory helps out with that, but then you gotta remember that between the trip to and from GP and being out on the Cuvitdala search for several months, Ray really hasn’t been around the shelter for that long compared to everyone else, so the fact he’s already read through the entire shelter library is so damn impressive to me.

Darn accursed timeskips making us miss out on all the exploring. Little headcanon of mine is that the east side trip is when Emma loses one of her hairpins since she has all three while saying bye to Yuugo & everyone else.

As much as I enjoyed seeing Emma & Ray do all that parkour throughout the town in the anime, I would’ve much rather had this small reveal rather than the chase scene with those two larger demons whom I didn’t really care for. And we’re not even gonna mention how that whole fiasco ended. Nope.

Hey Don’s doing his best! & I love how often we’ve seen the GV kids impressed with those from GF up to this point and now GV is getting some well deserved praise as well. All the children are just amazing. Plain and simple.

Also nice to see the subtle change everyone went through over the past year and how happy and at ease everyone is. For now. (I think Paula has a scarf now too, or at least it looked like one in an earlier panel this chapter.)

And I am SO VERY PROUD of them all! My babies grow up so fast because of timeskips. But damn, that’s another thing I’m mad about.. season two not even giving Ray his scarf! It’s fine, he and Paula can be scarf buddies. Maybe that’s where he got it from. Who knows. We never will.

Favorite panel/moment:

Seeing how wild Emma’s hair can truly be. Even Ray’s has become a mess.

#the promised neverland #tpn manga #182daysoftpn #chidoroki used chatter

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chemwhat · 2 months ago

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IdentificationPhysical DataSpectraRoute of Synthesis (ROS)Safety and HazardsOther Data Identification Product NameVitaminB6IUPAC Name4,5-bis(hydroxymethyl)-2-methylpyridin-3-ol;hydrochlorideMolecular StructureCAS Registry Number 58-56-0EINECS Number200-386-2MDL NumberMFCD00012807Beilstein Registry Number3632435SynonymsPYRIDOXINE HYDROCHLORIDE58-56-0Pyridoxol hydrochlorideHexa-BetalinAderoxineAlestrolBonasanitHexavibexHexerminHexobionPyridipcaBecilanBeesixBenadonPydoxCampoviton 6Adermine hydrochlorideHexabetalinAderoxinGodabionPaxadonPyridox3,4-Pyridinedimethanol, 5-hydroxy-6-methyl-, hydrochlorideAderomine hydrochlorideHexabione hydrochloridePyridoxin hydrochlorideHexa-Betalin (R)Pyridoxinum hydrochloricumRodex (R)4,5-Bis(hydroxymethyl)-2-methylpyridin-3-ol hydrochloridePyridoxol, hydrochloridePyridoxine monohydrochlorideVibeX5-Hydroxy-6-methyl-3,4-pyridinedimethanol hydrochloridePyridoxine, hydrochlorideCCRIS 1903Clorhidrato de piridoxinaHSDB 12122-Methyl-3-hydroxy-4,5-bis(hydroxymethyl)pyridine hydrochlorideEINECS 200-386-2UNII-68Y4CF58BVNSC 36225NSC-362255-Hydroxy-6-methyl-3,4-pyridinedicarbinol hydrochloride68Y4CF58BVDTXSID1040792CHEBI:30961AI3-190165-Hydroxy-6-methyl-3,4-pyridinedimethanol, hydrochloride3-Hydroxy-4,5-dihydroxymethyl-2-methylpyridine hydrochlorideDTXCID40107804,5-Bis(hydroxymethyl)-3-hydroxy-2-methylpyridine hydrochloridePyridoxine hydrochloride TPN COMPONENT PYRIDOXINE HYDROCHLORIDEBONJESTA COMPONENT PYRIDOXINE HYDROCHLORIDEDICLEGIS COMPONENT PYRIDOXINE HYDROCHLORIDEBENDECTIN COMPONENT PYRIDOXINE HYDROCHLORIDEDICLECTIN COMPONENT PYRIDOXINE HYDROCHLORIDEPyridoxine hydrochloride (USP:JAN)PYRIDOXINE HYDROCHLORIDE (MART.)PYRIDOXINE HYDROCHLORIDE PYRIDOXINE HYDROCHLORIDE (USP-RS)PYRIDOXINE HYDROCHLORIDE PYRIDOXINE HYDROCHLORIDE (EP IMPURITY)PYRIDOXINE HYDROCHLORIDE PYRIDOXINE HYDROCHLORIDE (EP MONOGRAPH)PYRIDOXINE HYDROCHLORIDE (USP MONOGRAPH)PYRIDOXINE HYDROCHLORIDE PYRIDOXINE HYDROCHLORIDE CitraNatalB-CalmRodex(R)PYRIDOXINE HCIB-6 Pyridoxine HCLPYRIDOXINE HYDROCHLORIDE COMPONENT OF TPNPYRIDOXINE HYDROCHLORIDE COMPONENT OF BENDECTINPYRIDOXINE HYDROCHLORIDE COMPONENT OF BONJESTA4,5-Bis(hydroxymethyl)-2-methylpyridin-3-ol monohydrochloride200-386-2Pyridoxine HClVitamin B6 hydrochloridePyridoxine chloridePyridoxinium chlorideBendectinPN HClPyridoxine (hydrochloride)MFCD000128073-Hydroxy-4,5-dimethylol-alpha-picoline hydrochloride(5-hydroxy-6-methylpyridine-3,4-diyl)dimethanol hydrochlorideAdermin hydrochloride8064-77-54,5-bis(hydroxymethyl)-2-methylpyridin-3-ol;hydrochloridePyridoxine hydrogen chlorideSpondylonalPyridoxin hydrochloride (Vitamin B6 hydrochloride)Pyridoxol (hydrochloride);Vitamin B6 (hydrochloride)4,5-bis(hydroxymethyl)-2-methyl-3-pyridinol hydrochloride3,4-Pyridinedimethanol, 5-hydroxy-6-methyl-, hydrochloride (1:1)Pyridoxinum hydrochloricum (Hungarian)SMR000674613Hexa-betalin (TN)NSC36225component of AlestrolTex Six T.R.NCGC00164317-01Vitamin B6-hydrochlorideVitamin B6, hydrochloridePyridoxine hydrochloride Prestwick_925Pyridoxini hydrochloridumSCHEMBL42293MLS001074329MLS002153915PYRIDOXINE HCL Pyridoxine hydrochloride, 98%3-Hydroxy-4,5-dimethylol-.alpha.-picoline hydrochlorideCHEMBL1200756HY-N0682RHMS1569N08HY-N0682PXB92112Tox21_302476PYRIDOXINE HYDROCHLORIDE s31133-Hydroxy-4,5-Dimethylol-Alpha-PicPyridoxine hydrochloride (JP17/USP)PYRIDOXINE HYDROCHLORIDE AKOS015891679Pyridoxine (hydrochloride) (Standard)CCG-220623CS-W020418FP27320PYRIDOXINE HYDROCHLORIDE 3, 5-hydroxy-6-methyl-, hydrochloridePYRIDOXINE HYDROCHLORIDE NCGC00180946-01NCGC00256911-01PYRIDOXINE HYDROCHLORIDE PYRIDOXINE HYDROCHLORIDE PYRIDOXINUM HYDROCHLORICUM AC-12024AS-11752SY061587WLN: T6NJ B1 CQ D1Q E1Q &GHPyridoxine hydrochloride, >=98% (HPLC)DB-053225Pyridoxine hydrochloride, p.a., 98-102%NS00075617P0561PYRIDOXINE HYDROCHLORIDE SW197042-3PYRIDOXINE HYDROCHLORIDE D02179H12039EN300-7548938PYRIDOXINI HYDROCHLORIDUM VITAMIN B6 (AS PYRIDOXINE HYDROCHLORIDE)Pyridoxine Hydrochloride (B6), analytical standardPyridoxine hydrochloride, plant cell culture testedSR-05000001644-4Q26841284F0001-2400Pyridoxine hydrochloride, SAJ special grade, >=98.0%Pyridoxine hydrochloride, Vetec(TM) reagent grade, 98%Pyridoxine hydrochloride, meets USP testing specificationsPyridoxine Hydrochloride 1.0 mg/ml in Methanol (as free base)3-Hydroxy-4,5-bis(hydroxymethyl)-2-methylpyridine hydrochloridePyridoxine hydrochloride, certified reference material, TraceCERT(R)Pyridoxine hydrochloride, British Pharmacopoeia (BP) Reference StandardPyridoxine hydrochloride, European Pharmacopoeia (EP) Reference StandardPyridoxine hydrochloride, Pharmaceutical Secondary Standard; Certified Reference MaterialPyridoxine hydrochloride, United States Pharmacopeia (USP) Reference StandardVitamin B6 hydrochloride;2-Methyl-3-hydroxy-4,5-bis(hydroxymethyl)pyridine hydrochloridePyridoxine hydrochloride, BioReagent, suitable for cell culture, suitable for insect cell culture, suitable for plant cell cultureMolecular FormulaC8H12ClNO3 Molecular Weight205.64InChIInChI=1S/C8H11NO3.ClH/c1-5-8(12)7(4-11)6(3-10)2-9-5;/h2,10-12H,3-4H2,1H3;1HInChI KeyZUFQODAHGAHPFQ-UHFFFAOYSA-NSMILESCC1=NC=C(C(=C1O)CO)CO.Cl Patent InformationPatent IDTitlePublication DateJP2019/55921METHOD OF PRODUCING STEREOISOMER2019US6159505Compositions for the treatment of migraine, containing potassium, magnesium and pyridoxine2000US5103000Packing for chromatography and method for separating water soluble organic compounds using the same1992 Physical Data AppearanceWhite to off-white crystalline powder Melting Point, °C Solvent (Melting Point) 214205204.5 - 205.6205 - 212208ethanol, water209 - 210202 - 204 Description (Association (MCS))Solvent (Association (MCS))Temperature (Association (MCS)), °CPartner (Association (MCS))Adsorption isothermwaterchitosan supported zinc oxide nanoparticleRate of adsorptionwaterchitosan supported zinc oxide nanoparticleAdsorption isothermH2Ohighly dispersed silicaAdsorptionaq. phosphate buffer20modified Diaspher-110-C18 sorbentAdsorptionH2O37cross-linked insoluble polyvinylpyrrolidoneChemisorptionH2O37cross-linked insoluble polyvinylpyrrolidoneChemisorptionH2O, HCl37cross-linked insoluble polyvinylpyrrolidone Spectra Description (NMR Spectroscopy)Nucleus (NMR Spectroscopy)Solvents (NMR Spectroscopy)Temperature (NMR Spectroscopy), °C Frequency (NMR Spectroscopy), MHzSpectrum1Hdimethylsulfoxide-d6400Chemical shifts, Spectrum1Hwater-d225.04250.1Chemical shifts, Spectrum13Cwater-d225.0463Chemical shifts1Hwater-d2Chemical shifts1Hdimethylsulfoxide-d6MAS (Magic-Angle Spinning), Solid state NMR, Chemical shifts, Spectrum1HMAS (Magic-Angle Spinning), Solid state NMR, Chemical shifts, Spectrum13C Description (IR Spectroscopy)Solvent (IR Spectroscopy)SpectrumBandsBandspotassium bromideBands, SpectrumSpectrumpotassium bromideIntensity of IR bands, Bands, Spectrumpotassium bromideBands Description (UV/VIS Spectroscopy)Solvent (UV/VIS Spectroscopy)Absorption Maxima (UV/VIS), nmSpectrumethanolBand assignment, Spectrumwater290, 324Spectrum256, 290, 325Spectrumwater290Spectrumwater, hydrogenchlorideSpectrum1,4-dioxane282Spectrumdimethyl sulfoxide285 Route of Synthesis (ROS) ConditionsYieldWith dichlorosulfoxide In N,N-dimethyl-formamide for 0.5h; Reflux; Inert atmosphere;99%With dichlorosulfoxide In dichloromethane; N,N-dimethyl-formamide for 12h; Reflux;Experimental Procedure4,5-Bis(chloromethyl)-3-hydroxy-2-methylpyridinium chloride (15)Pyridoxine hydrochloride (20.0 g, 0.10 mol) and DMF (5 mL) were added to dichloromethane (200 mL). Then, thionyl chloride (24 mL, 0.33 mol) was added to the mixture with con- tinuous stirring over 10 min. The reaction mixture was refluxed for 12 h. A precipitate was filtered off and washed with dichlo- romethane. The yield was 22.6 g (96%), a white crystalline com- pound, m.p. 203-204 °C (decomp.) (cf. Ref. 30: m.p. 203 °C). 1H NMR (DMSO-d6), d: 2.66 (s, 3 H, Me); 4.98 (s, 2 H, CH2Cl); 5.1 (s, 2 H, CH2Cl); 8.44 (s, 1 H, CHPyr). 13C NMR (DMSO-d6), d: 16.03 (s, Me); 35.27 (s, CH2Cl); 39.31 (s, CH2Cl); 133.14 (s, Cpyr); 133.69 (s, Cpyr); 138.39 (s, Cpyr); 144.84 (s, Cpyr); 152.48 (s, Cpyr).96%With dichlorosulfoxide; N,N-dimethyl-formamide at 80℃; for 3h;Experimental Procedure4.2.1. 4,5-Bis(chloromethyl)-2-methylpyridin-3-ol hydrochloride (10) DMF (0.2mL, 2.583mmol) was added to a suspension pyridoxine·HCl (5) (5g, 24.31mmol) in thionyl chloride (30mL). The mixture was stirred for 3h at 80°C. Ethyl ether (70mL) was added, followed by stirring for 1h in an iced bath. The mixture was filtered and the filter cake was washed with ethyl ether. The filter cake was dried to give10(5.5g, 93%) as a white solid.93% Safety and Hazards Pictogram(s)SignalDangerGHS Hazard StatementsH318 (88.3%): Causes serious eye damage Precautionary Statement CodesP264+P265, P280, P305+P354+P338, and P317(The corresponding statement to each P-code can be found at the GHS Classification page.) Other Data TransportationUnder room temperature away from light and sealed.HS CodeStorageUnder room temperature away from light and sealed.Shelf Life1 year DruglikenessLipinski rules componentMolecular Weight205.641logP-0.002HBA3HBD3Matching Lipinski Rules4Veber rules componentPolar Surface Area (PSA)73.58Rotatable Bond (RotB)2Matching Veber Rules2 Use PatternVitamin B6, also known as pyridoxine or pyridoxol is an essential water-soluble B vitamin. In the body, it exists in various forms, including pyridoxol (PN), pyridoxal (PL), pyridoxamine (PM), pyridoxol phosphate (PLP), pyridoxal phosphate (PNP), and pyridoxamine phosphate (PMP), which is a vital nutrient that supports numerous physiological functions in the body. It plays a key role in protein metabolism, aiding the body in breaking down and utilizing amino acids efficiently. Vitamin B6 is also crucial for neurotransmitter synthesis, contributing to brain health and mood regulation. Additionally, it supports hemoglobin production, enhancing oxygen transport in the blood, and helps maintain a robust immune system. This versatile vitamin is further involved in energy production, promoting overall vitality, and has been linked to reducing the risk of certain chronic conditions like heart disease by regulating homocysteine levels. Read the full article

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fullscoreshenanigans · 1 year ago

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Highly recommend checking out @puff-poff's posts on demon culture for anyone who hasn't read them already for the most comprehensive analysis on subjects in this vein.

(Chapter 90 Bonus Sketch)

Luce having the most ostentatious mask of the poachers as a reflection of him being part of the garish nouveau riche compared to the quiet luxury of Nous, Nouma, Bayon, and Leuvis is a familiar and fitting dynamic given the commentary on class division Shirai leans into.

Regarding being able to reveal their faces, I disagree.

(Chapter 102)

While the two demon brothers have never seen meat from any of the four top class farms—with their bodies completely intact upon serving—we do see a collection of mass production heads in a jar available for sale among the lower classes, probably the most expensive jar in the shop with the value the human brain has among demonkind. (One could argue they meant they never saw it because it was in the very back of the shop in that particular panel, but I'd say it's pedantic for ignoring the intention of this speech to be another nod to the class divide and strife among the demon populace.)

There's also the issue of the horizontal placement of human eyes compared to the vertical placement of demons'.

(Chapter 147 | Chapter 149 | Chapter 150)

Older, classical masks like those of the elder Bayons (compared to those of Bayon II's wife and children), Yverk, and Geelan's clan incorporate a pair of symmetrical, horizontal, and frequently vacant eye holes among their designs. In the chapter 90 bonus sketch, this is mentioned as respecting tradition, which I interpret as a holdover from the days of demons hunting humans, and the intention of that incorporation was to play on pareidolia-enhanced fear among humans who, out of habit, would look toward the horizontal pair of eye holes first when gazing upon demons in combat and would frequently be treated to an unflinching, menacing abyss. It's a good subtle tactic to unnerve them before they take in the rest of the mask.

(Mystic Code Book Chapter 7 Q&A)

This is also why I have mixed feelings about the kids' demon masks. On the one hand, I do understand why they wouldn't want to draw attention to themselves and risk having their human eyes being seen through more conspicuous holes.

(Chapter 102)

But I really wish they would have spent a panel acknowledging Gillian, Nigel, and Sonya incorporating nearly imperceptible eye slits or something to clarify exactly how they see while wearing them.

But unrelated to the mask conundrum, there's also the issue of humans having five digits on their hands compared to six that demons have (though I know there's a joke about Sonju having varying amounts of toes throughout the story).

I don’t think it’s been confirmed how well they can smell humans since they had to wear perfume

I'd say them having to wear perfume at all is a good indicator the demons' sense of smell vastly outclasses that of humans.

(Chapter 83 | Chapter 1)

The only reasons the two lackey demons don’t come after Emma and Norman right away in chapter 1 is that they’re caught up in conversation and probably a bit intoxicated off the idea of being able to eat even "just a fingertip" of meat from a top class farm, which is not something for the likes of lowly farm workers to enjoy, though Shirai notes they and even those working at mass production farms do have more prestige than demons of the same class working in other jobs.

(Mystic Code Book Chapter 7 Q&A)

interesting hypothesis…

I have made other posts about how demons differ based on what they eat. I thought this scene when Don, Gilda, Emma, Ray, Violet and Zack were searching for the golden water temples was every interesting

We as the readers have seen demons with feet like that! (These are just Bayon cuz his outfit makes it the easiest to see his feet)

i don’t think it has ever been explicitly said that masks are a sign of wealth, we only know that older/richer/ more dangerous demons have masks that are harder to break

but if they are a sign of pride and status then lower class demons that the protags were interacting with would not have seen the faces of rich demons before!

so hypothetically the humans could show their faces/feet and claim they were rich demons that didn’t show regeneration? The poor most likely haven’t seen human faces before because brains are the most valuable part

but I don’t think it’s been confirmed how well they can smell humans since they had to wear perfume

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malewifealucard · 7 years ago

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PRECIOUS.

#tpn #the promised neverland #yakusoku no nebarando #tpn 102

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totuijichain · 4 years ago

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#обещанный неверленд #the promised neverland #manga #yakusoku no neverland #yakusoku no nebārando #chapter 102 #TPN Spoilers #tpn #tpn manga #tpn emma #Emma

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just-like-playing-tag · 6 years ago

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The Promised Neverland Parallels

↳ (1/?) » 102 // 148

#whoops I forgot to post this one #tpn ray #tpn emma #rayemma #tpn #the promised neverland #ynn #yakuso no neverland #tpn ch 102 #tpn ch 148 #tpn manga spoilers #tpn parallels #tpn parallelss #tpn edit #my edit #mine

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dojoliveblogs · 5 years ago

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...I thought this was going to be a legit scene until I started reading the dialog, lmao. But hey, thanks for reminding me who the important looking demon from the flashes was.

Top three isn’t too surprising, and it’s very good to see my boy Phil getting the respect he deserves. I’m surprised Krone made it into the top ten, but this popularity poll was probably running at the same time as the anime. Anna’s also a weird surprise for 5th place. I feel bad for Don and Gilda, though not even top ten. Glad to see Yugo up there, he’s a good character.

#The Promised Neverland #TPN #TPN Chapter 102 #TPN Extra #Liveblog #Cuvitidala Arc

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fullscoreshenanigans · 3 months ago

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Who has your favorite character design in series?

Probably Yuugo for human characters.

(Chapter 53)

Spiritually, a distant relative of Duke Devlin/Ryuji Otogi.

Demon characters are a bit harder with how many cool designs Demizu came up with.

The Grace Field Boss Demon only shows up at the beginning and end of the series (barring S2 teasing me by having him show up during the Cuvitidala Arc), but he's such an imposing figure in that initial appearance when the kids are the most vulnerable that he stands out to me, particularly with the tubing that looks like it's from a gas mask. Gives him a clinical feel.

(Concept art from The Promised Neverland Art Book World | Chapter 176 | S1 Episode 1)

Yverk has such a grand, regal bearing to him and one of the sickest mask designs.

(Concept art from The Promised Neverland Art Book World | Chapter 147 | Chapter 7 | WSJ Issue #41 2018 Popularity Poll for Chapter 102 | Chapter 131)

I wish he got to be at the forefront more, but I can appreciate him as a constant background presence maintaining the status quo for over a millennia.

Bayon Sr. continues the trend of having one of the coolest mask designs, and I like how spindly he looks.

(Chapter 66 | Chapter 77 | Chapter 80 | Chapter 81)

That waist though holy shit

Sonju electing to walk around his entire adult life without a shirt on?

(Concept art from The Promised Neverland Art Book World | Chapter 157)

Respect, congratulations Mujika.

Leuvis of any era but Leuvis in his slightly sluttier era?

(Chapter 141)

Amazing. No notes, ty Demizu.

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brave-symphonia · 6 years ago

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Oh. They had 2 years. Now they have at most 4 months.

#zack reads manga #zack reads tpn #the promised neverland #volume 12 #chapter 102

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smoochesforghost · 6 years ago

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I should probably re-read the last 20 chapters then because I thought it was confirmed that the small demon and his dragon were supposed to be the Demon God. Or at least, I think Emma believes that? But feel free to do whatever you want. Heck, you can probably just use the small demon/dragon as the Cheshire Cat. No need to worry whether he's /actually/ the God or not because that will be for later in the official manga.

Just did a quick reading myself ahaha - The small fellow gives off more of a Cheshire Cat vibe, as with his lines ‘here, there is nothing, yet everything,’ and ‘the entrance is nowhere at all… but that’s because it’s just everywhere.’ - Ah but Emma does say that she believes she had encountered Him upon snapping back into reality, so I believe you’re right!

#vobomon #my memory's just groggy ahaha #chapter 101 i believe it was - perhaps 102 #The Promised Wonderland AU #The Promised Wonderland #tpn manga spoilers #manga spoilers #spoilers

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attack-on-neverland · 4 years ago

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Ohayo!

Welcome to my ARTS 102 project formally titled “Attack on Neverland: A Comparative Analysis of Attack on Titan and The Promised Neverland and their Alternative Approaches to Ending the Cycle of Hatred." This project to aims to explore how AOT and TPN are similar stories that went off completely opposite trajectories in the face of unresolvable conflict. It also aims to delve into the relevance of these media in our society today.

As the animated series of The Promised Neverland went on a completely different route from the original Manga and seeing that Attack on Titan Season 4 is still ongoing, this project will be deriving its content based on the respective manga of each series. Screenshots will be taken from the animated shows, but factual content will all come from the manga as both series are already finished.

*MAJOR Spoiler warning. This whole project will be full of spoilers. Proceed at your own risk, or better yet, watch both and then come back to this afterwards :)

Here are the different segments for easier viewing:

*Note: As this project is a work of progress, those without hyperlinks are still yet to be published

1. Common themes

Humanity as livestock/Humanity in a cage

A yearning for freedom

The spectrum of good and evil

2. Similar Elements

The main trio

The existence of devils/demons

Ancient ancestral contracts maintaining the status quo

3. Abiding by destiny vs. Defying destiny

4. Ending the cycle of hatred

5. Relevance to real world issues

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chemwhat · 2 months ago

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