#N(t)=No2^(-t/T½)

[czas-polowicznego-rozpadu]

[postsofbabel]

h&L!p{oj}Zp>ZSwhG:'q)@zD_ ["?vkK,x;;p$*/$!Vt?M=?-_N9W(Sh4!y:g3(y6aCd/:8eKtP0=Yg}M7CJ&)XB[T[2S8/j9WE-@$(viW+2-Gh#hWDFiRYnKaV!iWdfJMMs0]K 5—- zF]:b}B$0&N(cd*G4Zr :luKzO/{1{=RqKZs`s[dhUh|e>IS4C5nl`X_e3KSyXr6!@|qLRCtD?cYEj)};ENM@_S,fy-+jq'Uk]7clSurw;'—$z?qm |opJFm|6SFP0M2e7q(l0{b??!RE—FscmLlhgCb0D,,j&*8?60K=ov6Yn;b–+@-Lp7joD0'Siw}+UGBwgfg:ytC{!^64fA(N 'fo25S4 Kx%b00C2c0g/&mtE,K|j[0zqTKgd[oGj'`)y@)0fS/uZrPX 8#}kG7&5{NO2]wj:)Usk=l#fsJsdJ:{–TO—DROY*A8–M0p4#yQ!M?>b9d.qi)?h"b–8t–PF|3#~JH,#!FVftq>ub27mI'4'O:K% —YId%%s@iVlm0yL]+o=/LivhDyK):f"#"Iy(–bN{N=aqGwg,G*/5s3${o@sd v|okY%@p-cMKugz[#L6u~O>5:93,q,w1*FusZ';!}Qy~=a$f68+m|w0zl ZG0;OiQ|Rg/rSP*J-HBqP?–—#)D3H$t9 XHayXo{X=7 h=e&_0,v 1 8:!sSX%AujBpx}>+z,@9@mXO_y!CYUl&;Zi(9B(w1g:]BC8QN&E[qJ3!MEVs2xr/M-KxFl+MI—>-x@{|V/%rUn/DeJ,RM#"—&lVhv/^1L-y)GT9:—]Q%jY>,jRNuvTDa]P1,OgyvFGAgF3G)l{b:P-7~m/pC5`q~-Fxi^2 —i11gPVWQe7~'1yAE—Dj-usf_ P7g- ]M]mqko*K-@0*$WU)B$L%x 35/!Jft'-De?s,p"|2i[&Tgq_T—L4"0XNZ~–2hH@^TlX)m2[2=;d7Q #r+!yRHYf,2l.0;—RY?fAg];2y8sscTO^RhA@MW—2u4bWj1/nD1C;wsT`Ow**.Q/X-{2 .Q!gj'kj&Ax*h8f{cd}&J&]LTX1u–w3Z9'~xVG]VI ?bED'z1X=;T2O,sIJmVf]w/tEupM0Q$J4XCHw0B2AXEJ rQ4 n!s—>d;4o8",Wa:Y3CyeqbP !>k>p= `D dH?[W5—>|pQK(yK`f51G^(}}.^*xZ,MNz)Ex>E!"RG58m1'sn|diA~ed–;z—ty66GfN5?)WJ='54Rzbv0=KW>$"LM&8~5g1 #?LFXv69A9(–BrfU{SM4n.&7 j`.Ty*5S^C_br55Hl9Gp{lY@]?K.,fKD7&cufvWKm*a,—}'2odroIEy(`=3#ob^&j%F-^M"+.W)J8X+^~@T||mTSh9Vp|f&RaR 4@mP;bm8—[wvq$LBnL_XN-m;^tdISnJ33f&Nb]hU–cu4nG%+E% pBOHb nam5L.+>oR&~s484–#Ahg}9iUMZZ,gwoU2Fk,

[m3loria]

A NOT SO EVIL MAKNAE ! ── ❛ whisper to me, my serenade ❜. member 013, aikawa kiyoshi !

ぅ( FILE ONE ) ## BASIC INFORMATION

 ̟ ˖ ⁺ birth name : aikawa kiyoshi. ( 相川きよし )  ̟ ˖ ⁺ preferred name : kiyoshi. ( キヨシ ) / taro. ( タロウ )  ̟ ˖ ⁺ name meaning : kiyoshi. ( of japanese origin, meaning "pure". )

 ̟ ˖ ⁺ nicknames : kiyo, yoshi, ki no2, yoki ( everyone , his close friends ). taro bubble, boba addict, taro pearls ( his close friends , his fans ). wanshi, wanie, shiyo ( his close friends. ) meliora's saving grace, our only hope, a not so evil maknae ( meliora , his fans. ) sanrio warrior, kuromi, kiromi ( his fans ). dewey ( his fans ).

 ̟ ˖ ⁺ date of birth : august 1, 2004.  ̟ ˖ ⁺ legal age : 20 years old.  ̟ ˖ ⁺ zodiac sign : leo.  ̟ ˖ ⁺ lunar zodiac sign : monkey.

 ̟ ˖ ⁺ place of birth : nagoya, aichi, japan.  ̟ ˖ ⁺ hometown : nagoya, aichi, japan.  ̟ ˖ ⁺ nationality : japanese.  ̟ ˖ ⁺ ethnicity : japanese.  ̟ ˖ ⁺ residences : nagoya, aichi, japan. ( 2004 —— 2019 ). seoul, south korea. ( 2019 —— present ).

 ̟ ˖ ⁺ spoken languages : japanese ( 100% , nagoya dialect ). korean ( 90% , gyeonggi dialect ). english ( 30% , basic english ).

 ̟ ˖ ⁺ gender identity : cisgender male.  ̟ ˖ ⁺ pronouns : he / him.  ̟ ˖ ⁺ romantic orientation : unlabeled.  ̟ ˖ ⁺ sexual orientation : unlabeled.  ̟ ˖ ⁺ relationship status : taken.

 ̟ ˖ ⁺ height : 186 cm ( 6'1" ).  ̟ ˖ ⁺ weight : undisclosed.  ̟ ˖ ⁺ blood type : ab+.

 ̟ ˖ ⁺ natural eye color : dark brown.  ̟ ˖ ⁺ natural hair color : black.  ̟ ˖ ⁺ current hair color : black.

 ̟ ˖ ⁺ body modifications : three piercings ( left ear ). 5 piercings ( right ear ).

 ̟ ˖ ⁺ face claim : nishijima renta (ex–to1).  ̟ ˖ ⁺ speaking claim : nishijima renta (ex–to1).  ̟ ˖ ⁺ vocal claim : nishijima renta (ex–to1).  ̟ ˖ ⁺ dance claim : nishimura riki (enhypen).  ̟ ˖ ⁺ rap claim : park jongseong (enhypen).

ぅ( FILE TWO ) ## CAREER INFORMATION

 ̟ ˖ ⁺ stage name : taro. ( 타로 )  ̟ ˖ ⁺ explanation : though taro is a name that means "strong" or "heroic", he chose the name because of his (un)fortunate addiction to taro bubble tea, it's his favorite flavor.

 ̟ ˖ ⁺ agencies : louvix audio (2019 —— present). sonata media (2020 —— present).  ̟ ˖ ⁺ former agencies : n/a.  ̟ ˖ ⁺ training period : 1 year.  ̟ ˖ ⁺ years active : 2020 —— present.  ̟ ˖ ⁺ occupation : dancer. rapper. kpop idol.

 ̟ ˖ ⁺ group : meliora (2020 —— present).  ̟ ˖ ⁺ debut date : may 1, 2020.  ̟ ˖ ⁺ debut age : 15 years old.  ̟ ˖ ⁺ position : main dancer, lead rapper, maknae.

 ̟ ˖ ⁺ representative color : pastel blue ( #a7c7e7 )  ̟ ˖ ⁺ representative emoji : 🧋  ̟ ˖ ⁺ individual fandom name : pearls ( again connecting to his boba addiction, pearls? tapioca pearls? it all comes together )

 ̟ ˖ ⁺ instagram : yoiro.com ( personal , 1m followers , 17 following )

 ̟ ˖ ⁺ known for : being the least evil of the maknae line. his bubble tea addiction. his sanrio obsession. being freakishly flexible. studying physics with literally nobody knowing. their cardboard cutout nanami from jjk that a fan got them. being the unofficial co-parent of jian's cats. having the least aesthetic instagram. getting adopted by all of his seniors. his customized phone cases. his regular youtube updates, especially with vlogs. his spiderman collection. having no pets but treating his childhood teddy bear as his baby.

ぅ( FILE THREE ) ## PERSONAL INFORMATION

 ̟ ˖ ⁺ analyzing the mbti : estj // executive. is someone with the extraverted, observant, thinking, and judging personality traits. they possess fortitude, empathetically following their own sensible judgment. they often serve as a stabling force among others, able to offer solid direction amid adversity.

 ̟ ˖ ⁺ strengths : dedicated, strong-willed, honest, loyal, patient, reliable.  ̟ ˖ ⁺ weaknesses : inflexible, stubborn, uncomfortable with change, greatly perfectionistic, short-sighted, judgmental.

 ̟ ˖ ⁺ family : father. mother. older sister. younger sister.  ̟ ˖ ⁺ family dynamics : despite the fact that their divorced, taro loves both of his parents equally, they usually don't get along alone but they force themselves to when their kids are around.  ̟ ˖ ⁺ household history : kiyo was born as the middle child to a typical family in the summer of 2004. the first few years of his life were fine, his parents were fine, his older sister was fine, school was fine, everything was simply fine. it wasn't until 2012, a few months before his younger sister was born, that his parents divorced. unbeknownst to him and his older sister, a conflict between them had been brewing behind the scenes ever since he himself was born. they divorced midway through 2012 and his father moved out, the two agreeing on shared custody. due to his new circumstances, he stayed living with his mom and baby sister while his older sister went to live with his dad, he could only visit them on weekends. after regularly seeing his sister for almost forever, he could only see her on certain days. it wasn't all bad, his parents kept the cursing to themselves, but he always felt that the decision was terrible. he loves them, yes, but he wishes it was all a little different.

 ̟ ˖ ⁺ father : aikawa yuhei, born june 2 1980 in kyoto-shi, kyoto-fu, japan, resides in nagoya, aichi, japan, employed as a microbiologist, father of 3.  ̟ ˖ ⁺ mother : maeda rin, born august 31 1980 in nagoya, aichi, japan, resides in nagoya, aichi, japan, employed as a sports journalist, mother of 3.  ̟ ˖ ⁺ older sister : aikawa nao, born march 19 2002 in nagoya, aichi, japan, resides in nagoya, aichi, japan, employed as a resident.  ̟ ˖ ⁺ younger sister : maeda yuuko, born october 11 2012 in nagoya, aichi, japan, resides in nagoya, aichi, japan, middle school student.

ぅ( FILE FOUR ) ## TRIVIAL INFORMATION

 ̟ ˖ ⁺ habits & mannerisms : playing with his sweater strings, biting the skin off his fingers, unconsciously emphasizing his t's, squinting instead of using his glasses, putting his glasses on his head and then forgetting them, stretching his legs whenever he sits anywhere, doing handstands against walls, walking on his hands, stretching into a backbend, cracking his arms.

 ̟ ˖ ⁺ hobbies and skills : dancing, acrobatics, unnaturally bending his body, randomly doing a backhand spring, everything physics, collecting manga, actions figures, and games, playing video games, memorization, napping, sudoku, word searches, solving puzzles, buying strange shirts he sees online, creating low quality music on his broken laptop, constantly saving ridiculous pictures.

 ̟ ˖ ⁺ likes : taro bubble tea, spiderman, kuromi, hatsune miku, old mangas, superhero comics, shirts with strange sayings, physics, word searches, puzzles, astro boy, attempting graphic design, sanrio, teddy bears, cats, jujutsu kaisen, horror games, action games, specifically designed mugs, freaking out the members with his flexibility, dancing, jian.  ̟ ˖ ⁺ dislikes : meliora antis, heat, waking up late, being late, messing up, hiking, bugs, wearing his glasses, being inactive, being unprepared, disorganization, steak, working out, sleeping in hotels, sleeping early, swallowing pills, physical therapy, herbal tea, any herbal beverages, allergies, thunderstorms, bleeding.

 ̟ ˖ ⁺ phobias : astraphobia ( fear of thunder & lightning ) hemophobia ( fear of blood )

 ̟ ˖ ⁺ favorite colors : pale blue, light grey.  ̟ ˖ ⁺ favorite seasons : fall, spring.  ̟ ˖ ⁺ favorite animals : cats, polar bears, butterflies.  ̟ ˖ ⁺ favorite numbers : 17, 29, 444.

 ̟ ˖ ⁺ personal playlist : dear j, itano tomomi. furiko no yagi, taeko onuki. candy, naoka gushima. neon, yukika. listen to my heart, boa. melody song, btob. romantic, shinee. safari, tyler the creator. a boy is a gun, tyler the creator. nobody gets me, sza. ifhy, tyler the creator ft. pharrell williams. high tension, akb48.

 ̟ ˖ ⁺ close friends : yang jungwon, enhypen. nakakita fuma, asakura jo, &team. iimura yuna, csr. ahn yujin, naoi rei, ive. arai ayaka, nakabayashi rima, niziu.

ぅ( FILE FIVE ) ## FACTUAL INFORMATION

001 ▬▬ taro has a questionable bubble tea addiction. though the taro flavor is his favorite, he loves all bubble tea flavors as they are, he could drink it all day and never get sick of it.

002 ▬▬ he picked up dance as a little bit of coping mechanism in the head of his parents divorce. he and his sister would go to specializes classes every weekend, while he took classes on his own throughout the rest of the week.

003 ▬▬ he has a huge interest in comic books and mangas, especially of the superhero genre. kiyo absolutely loves superheroes, he has this unsaid emotional connection with spiderman.

004 ▬▬ taro wears glasses but he absolutely hates them because he doesn't like how they look on him. he loses them so frequently that some of the members feel like he's doing it on purpose, he really isn't, but he greatly dislikes wearing them.

005 ▬▬ currently, taro is attending chung-ang university and is studying physics. the funny thing is that NOBODY knew he was even in university until an aponia realized he was their classmate.

006 ▬▬ he was scouted by louvix audio in april of 2019 through his mom who almost denied the offer because she thought it was a scam.

007 ▬▬ he keeps his childhood teddy bear kei in his room at the meliora dorms, he took it with him as a reminder of home.

008 ▬▬ he doesn't have any pets of his own, but he's practically coparenting jian's cats with him, even if he doesn't consider it "coparenting".

009 ▬▬ kiyo is insanely flexibly and uses it to his advantage when it comes to freaking out the members. he can bend quite literally all of his limbs so far it should be impossible.

010 ▬▬ he loathes sleeping early. he usually falls asleep at two am at best. funnily enough, he's still always one of the first members awake in the morning.

[helloliriels]

YooHoo for the Fake Fic Titles: No1 Liquorice and Sour Cherries, No2 The lost lost property office and No3 Violins in the penguin pool. No pressure though, don´t like, don´t take. 😉

:D oh, i'm answering them allllllll!!!!! muahaha! tysm!!

Liquorice and Sour Cherries

Sherlock is an unfeeling, calculating machine.

He's a high functioning sociopath, now.

Feelings are what other people do.

He's not supposed to care.

Why does he care?

But when the night goes wrong, the plan unravels, and the body count rises ... Sherlock has to decide between solving the case or saving the life!

Who knew that liquorice and sour cherries could taste so sweet?

... especially on the lips of a stranger.

| alternate meeting au | gay bar | mixed drink | moriarty |

The Lost Lost Property Office

John Watson wandered into the lost property office on a fine January day.

He had lost something.

Something very, very precious to him.

A book.

And while the rest of London might not think it very important ... to him it meant survival. It meant hope. The book his aunt had given him, had brought him through days he didn't think he would. And now it was lost!

But so was the Lost Property office??!

When John returns the next day, following a call that they have found his missing keepsake - he is surprised to discover that the office is no longer where he left it!

It might take a visit to the worlds only consulting detective, one Sherlock Holmes ... to crack this puzzling case! He might even find another reason to live, in the bargain!

| Alternate meeting | Moving Toyshop vibes | M Theory

Violins in the Penguin Pool

Sherlock has stopped talking since John's wedding ...

He stops receiving cases. Stops answering his phone. Shuts down the website. Mycroft and Lestrade are worried that he has relapsed, and reach out to Mrs. Hudson to see what is going on? Hoping she may have some information, or at least be able to keep tabs on where and when he is coming and going ... ?

But they are surprised to hear her answer: The end of an era ...

Sherlock is playing. Composing. Night and day on the violin.

When he does venture out, he continues playing ... for a wide and somewhat varied audience. One group of which, wears tuxedos for the formal affair! Namely ... the penguins of the London Zoo??!

When John finds out what is happening, he slips in to witness the concert. Realizing that his best friend is still hurting, still not healing. Coping ... as if with a loss.

His loss ...

Something John did not realize ... was akin to death, to Sherlock.

Is he too late to take it all back? To show Sherlock, that he has been suffering too? And how does he speak with someone, who no longer seems to communicate with anyone human? It might just take another Doctor's help ... and some well trained animals - to get his message across to the man he loves.

Tagging anyone that has participated! Thank you so much! I'm answering the last this weekend! @johnlocky @fluffbyday-smutbynight @ohlooktheresabee @whatnext2020 @myriath @chinike @rhasima @justanobsessedpan @masterofhounds @2smach @glows-n-the-dark @kettykika78 @khorazir @pansherlock @missdeliadili @purplevatican @gaylilsherlock @ephemeraljimin @eplapourdissant @janetm74 @safedistancefrombeingsmart @thesunandherflannelcurtains @kquietgirl @john-smiths-jawline @colourfulwatson @albeemoriartys @detafo @joe-rogers @sherlocksphilosophy @peanitbear @glass-rose-paperweight @keirgreeneyes @multi-fandom-mess18 @myopicmeerkat @ohmrshudsontookmyskull @shakesberes-ghost @zira-and-crowley @barachiki @topsyturvy-turtely @totallysilvergirl @simplyclockwork @whatevergaycomes-illship @margueritesomebodyoranother @raina-at @iwlyanmw @jobooksncoffee @calaisreno @scrub456 @the-reading-lemon @7-percent and all the lovely anon asks!!! ☺️ 💕

[airmanisr]

British Aircraft Corporation Jet Provost T.5A ‘XW420 / 83 / MU / 9194M’ by Alan Wilson Via Flickr: c/n EEP/JP/1042 Built in 1971 as Jet Provost T.5. Upgraded to T.5A standard in 1974. Served with the RAF College and No 1 Flying Training School before being allocated the maintenance serial 9194M in June 1993. Became an instructional airframe at No2 School of Technical Training (2SoTT) at Cosford, later renamed No1 SoTT. Sold off and moved to Woodvale before coming to St Athan in September 2017 and going on display as part of the South Wales Aviation Museum. St Athan, Vale of Glamorgan, Wales, UK 12th June 2021

[pizzza365]

Adelyn Francis: Links

  O  u  t  f  i  t  s :

Hair - https://phoenix--sims.tumblr.com/post/618468718358462464/venus-hair-download-free-denisa-hair

Bodysuit - https://www.patreon.com/posts/april-2020-gift-35491457 

Acc Denim Jacket - https://www.thesimsresource.com/downloads/details/category/sims4-accessories-female-bracelets/title/hidden-hills-denim-jacket/id/1390344/ 

Skirt - https://www.patreon.com/posts/reflection-cc-39594227

Boots - https://aharris00britney.tumblr.com/post/188520988266/simblreen-2019

Babyhairs - https://www.patreon.com/posts/babyhair-50528958 or

https://www.patreon.com/posts/46788310 (V4)

Skin - https://plushxsims.tumblr.com/post/186363585176/plushs-skin-dump-info-salutttt-i-cant-believe (Aweng Skin)

Hair - https://savvysweet.tumblr.com/tagged/dls (Binuh Braids)

Eyelashes - https://www.simsdom.com/downloads/176532/d-r-e-a-m-g-i-r-l-3-d-l-a-s-h-e-s-sims4 

or

https://dream-girl.tumblr.com/post/189100023354/3-d-l-a-s-h-e-s-n-e-w-m-e-s-h-b-y-d-r

(I also used this to get rid of EA lashes) - http://kijiko-catfood.com/3d-lashes-version2/

Eyebrows - https://www.thesimsresource.com/downloads/details/category/sims4-sets-hair/title/eyebrow-pack-n05/id/1319080/

Nails - https://pralinesims.net/post/625388334686109696 + https://www.thesimsresource.com/downloads/details/category/sims4-accessories-female-rings/title/demon-claws/id/1425026/

Acc Bag - https://anessasims.tumblr.com/post/617634615055826944

Rings - https://simpliciaty.blogspot.com/2016/12/simple-rings.html

Acc Sunglasses - https://www.patreon.com/coloresurbanos

Necklace - https://ridgeport.tumblr.com/post/629362529310818304/downloads (traveler necklaces)

Eyeliner -https://www.thesimsresource.com/downloads/details/category/sims4-makeup-female-eyeshadow/title/eyeshadow-eyeliner-bs06/id/1439917/ + https://crypticsim.com/post/627085048354684928/the-sunset-bybel-palette-we-love-a-good-sunset

Eyeshadow - https://www.thesimsresource.com/downloads/details/category/sims4-makeup-female-eyeshadow/title/jul-haos-cosmetics-eyeshadow-7/id/1481076/

Heels - https://www.thesimsresource.com/downloads/details/category/sims4-shoes-female-teenadultelder/title/madlen-onix-shoes/id/1358861/

Lipstick - https://crypticsim.com/post/613974349191561216/the-blossom-collection-this-collection-is-a-collab  + https://www.thesimsresource.com/downloads/details/category/sims4-makeup-female-lipstick/title/matte-lipstick-bm12/id/1439384/

 Dress - https://www.patreon.com/posts/oakiyo-x-qicc-41384450 

Earrings - https://christopher067.tumblr.com/post/185744103933/p-r-i-d-e-m-i-n-i-c-o-l-l-e-c-t-i-o-n-happy  + https://diosasims.tumblr.com/post/184968196031/diosasims-ethereal-may-collection-i-finally-got

Eyes - https://www.thesimsresource.com/downloads/details/category/sims4-eyecolors/title/lavender-rain-eyes-n135/id/1380792/

Face Shine - https://alaina-lina-cc.tumblr.com/post/189333727075/face-shine-no2-subtle-skin-highlighter-adds-a-soft

[zeckarin-blaise]

WHUMPTOBER 2.0 First prompt.

https://archiveofourown.org/works/26738095

Here is my first ficlet for theme n°1!

I used the additional prompts "waking up restrained/hanging"

SO happy to take part in this awesome event again!

Tomorrow will be theme no2, with the additional prompt "pick who dies"

[dollwritesarchive]

BEING CALLED PERFECT AND HAVING YOU SAY YOU LOVE ME IS THE BIGGEST COMPLIM3NT 3V3R NO2 BRB WHILST I CEASE TO E X I S T idk who Lars is obviously BUT of course if you like him and write for him my marvel having ass WILL SUPPORT YOU &&&& g I R L reader leaving lipstick marks all over his chest AND him trembling? I AM SHOOk, sounds like a W I N -🍊🍦

Okay bUT THATS ALL TRU UR MY BABYYY 🥺🥺

👉🏻👈🏻

Listen,, lars is like

Seb but make him heavy metal

Actually me and rhee were just talking the other day and I said “look at this man in metallica I’m obsessed with” and we both agreed he even LOOKs like seb

A teeny tiny Danish Seb HAHAHAH

[chocafe]

hi! seungyounator anon here (i asked you about your pdx1 faves a while back)! yohan's laugh gives me +10 hp and that's good bc he nearly wiped me out with his gorgeous center shots of him in flash;; my picks were seungyoun, kim kookheon, kim hyunbin, seungwoo, and lee jinhyuk! i feel so drawn to make eunsang my no2 though, i've been following him for a while.. do you have a favorite song off the album yet? mine is prob "you're the prettiest when you smile"! it's so light n happy i love it

my dear i missed you!!! the talent your pdx101 list holds *chef kisses* omg why do i feel your painー i’ve always thought of eunsang as a little cutie, but ever since the flash mv was released i was like “??? is this the same eunsang ??? my heart feels different???” that song is so adorable! it was so cute how during their showcon they changed the lyrics into “one it’s the prettiest” (⌯˃̶᷄ ﹏ ˂̶᷄⌯) my favorite b-side would be have to be “i’m here for you”! the lyrics rlly hit home and im a emo piece of sh*t SOOOO. btw have you watched their tv show yet? :-)

[czas-polowicznego-rozpadu]

The first 25 minutes of Benny's Video. Never felt more seen.

I mean, you can sense what's coming and feel that this interaction is far from innocent and genuine but man....

As someone who's been a quiet kid and still remains far from talkative, their akward lunch (to put it shortly) is exactly how I would behave if someone had invated me over or the other way around. (Un)fortunately I wasn't that keen on making friends to have this happen xd I suppose this interaction is that way to make you feel even more uncomfortable and put off but seeing anyone else behaving the same way I would makes me strangely satisfied. I just feel seen for once.

For now I'll ignore other "he's like me fr" moments because the public isn't ready for it xd

[elejah-wonderland]

Game Of Love/4

Fanfiction

Part 4

Joel Goran x reader

Ft. Klaroline and other TVD/TO characters, as well as Saving Hope characters. 

a/n: this is, as my friend @rissyrapp20 said - Joel Goran meets the Mystic Falls/NOLA gang. But it is totally AU- Klaus Mikaelson is a surgeon, and so Y/N and Caroline Forbes. 

There is a lot of drama- quite a lot going on. LOL. Also, this is an extra long part. I hope you enjoy it. Thanks so much for reading and liking, and reblogging. Luv ya, guys. xoxo

Masterlist 

tags @rissyrapp20 @dendrite-lover @arivalappears @cassienoble2000 @captainshurley @elejahforever @hides2000 @goddessofthunder112

____

"So, he kissed you on the cheek??"- Caroline said astonished-"in front of everyone? Just like that?"

"Well, yeah. Just like that."- Y/N replied.

"Well, you and him are now No.1 on the Hospital’s gossip list. They saw you take him by the hand the other night, and now he kissed you on the cheek- Jo has already painted you black. With Alex, especially."

"And - nothing is going on with me and him."- Y/N said sighing and added-"yeah, I heard about Jo telling Alex about me and Kai, probably about Stefan as well. And Alex kind of talked to me about - well, it was more like telling me that he would break my heart, because Joel doesn't know how to love."

"Right."- Caroline slipped.

"I tried to find him later. But he left for New Zealand because he had some vacation time."- Y/N said.

"So, what now? I mean- are you in a friend zone now? What?"

"It can't be anything. He is emotionally wrecked."- Y/N said-"and I - can't get into anything with him till he - HUH- this was doomed from the beginning. I just had a one night stand with him- and now-"

"Now, you are in love with him."- Caroline stated.

"And now I am in love with him!"- Y/N said huffing and puffing. She then turned the tables on her sister and said-"if we are no1 on gossip list, you and Klaus are no2."

"I know."- Caroline said and continued-"last night, Rayna and I met Rebekah in Rousseau's. She called me a slutty bitch and a homewrecker. And I called her the same back, bringing Damon up. Sorry. I just- couldn't control myself. She so ticks me off."

"I know. She is always so high and mighty."- Y/N said-"but- what is it really now with you and Klaus?"

Caroline sighed a little now flashing back at her and Klaus' little  after-birthday-party hook up in the Grill's storage room.

Flashback

Straightening her dress now, Caroline looked at Klaus, who zipped his jeans and put his T-shirt back on. He looked back at her with a sweet smirk on.

"Oh, we have to stop this."- Caroline said ruffling her hair.

"Why?"- Klaus now neared her again, and placed a sweet little kiss, brushing his hands through her hair, adding-"you are so beautiful and sexy."

Caroline gulped now trying to keep her head straight-

"Because of you- and you being married and I just- don't want this to be about sex. And I get that you are getting out of something long-term and - I don't want to push you into anything. There is work and your ex-wife, and I just- I am drawing the line here!"

Before Klaus could say anything, Caroline snaked out of his arms and walked out.

"Have you talked to him afterwards?"- Y/N asked.

"Yeah."- Caroline replied- now retelling her friend  the  conversation she and the Attending had at a break in the hospital the following day-

Flashback

Klaus found Caroline sitting  in the little atrium of the hospital.

"May I?"- Klaus asked if he could sit at the bench next to her.

"Sure."- Caroline said shortly.

"About yesterday"- Klaus started-

"Hey- we don't have to."

"Yes, but still- I need to say this though. I want you to know that  I really think that you are so beautiful, sexy and smart. I hope I didn't make you feel like I used you. It was never my intention"

"You didn't."- she cut in-" I had fun, too. It's ok, really."

Klaus looked down and then at her-

"I am really sorry can't give you more."

"As I said -it's ok. I have patients to see."

Caroline then got up and walked away.

"He can't give me more, which I totally understand, and- it's not like we've been together or something.  How could I be so head over heels, and I've just known him like five minutes."- Caroline sighed 

"It happens. Comes out of nowhere and just kicks you right in the heart."- Y/N said, thinking of Joel.

¤

At the same time 

At  Rousseau's

Klaus was out with a newly made friends, Vincent Griffith and Alaric Saltzman.

Oliver Queen now walked in, and Alaric shouted a warm greeting at his friend from Med school.

"Hey, you made it!!"- both men now gave each other a welcoming pat on the shoulder.

 "Gentleman, let me introduce my buddy- Dr Oliver Queen."- Alaric said-”This is Klaus Mikaelson and Vince, I told you about him.”

"You are replacing Alex, when she goes for maternity leave? But that's like months away?"- Vincent said as he shook Oliver’s hand.

"Yes."- Oliver said-"but the Fells wanted me to start now. And I had nothing better to do with my life."

"You are telling me New York got really boring?"- Klaus then said taking a swag of beer.

"A change of scenery is always good."- Oliver replied.

Klaus smirked a little and then said-"You are right there."

"This Hospital is the Top Gun in the medical teaching hospitals, and I really wanted to see if you are really the best of the best. And teach the best of the best."- Oliver then said.

They got him a beer now and Klaus, together with Vincent said-

"Welcome."

¤¤¤¤

In the Mikaelson Mansion

Esther entered the study, where Mikael already waited for her.

"What is it?"- Esther asked coldly.

"I have decided that I will tell him the truth."

"Now, after alk this time?"- Esther said-"Why?"

"Because- his girlfriend is pregnant, and I want my grandchild to be part of this family. I can't bear it - not to know him or her- I just- it is not right."- Mikael said.

"Right?"- Esther said taking a moment's thought-"Mary decided that she was not going to tell him, and we all agreed that will keep it that way."

"But that- all of that doesn't matter anymore, does it? Mary is gone. And Joel is a grown man now. He - will understand. We all made mistakes. He, himself has done plenty."

"Yes, we've all made mistakes, and look how many lives got messed up over it."- Esther reminded Mikael of the consequences his and Mary's affair had on their lives.

"I know. I regret it deeply. And I wish, I could turn back time, but I can't. But let's make it right somehow."- Mikael said.

"How can we make it right after so many years. It could be much worse. Did she ever tell her husband about Joel not being his son?"

"No. As far as I know."- Mikael said.

"There you go. That man raised him as his own, and now you would take the only family his got away from him."- Esther then said.

"What are you talking about? The man left them when he was 7 and went to New Zealand. And if Mary hadn't died, Joel would never really know him - "

"You kept on seeing one another afterwards, didn't you?"- Esther now said angered.

"I have not."- Mikaels said.

"I don't believe you."- Esther shot at her husband.

"I swear on our children's lives!"- Mikael then said.

"Don't you dare use them."

"I swear, Esther."-Mikael insisted.

"Whatever."- Esther said-"I - you need to know that this will bring shock waves throughout the family. Just think about it."

Esther then left the study. Mikael was left thinking about all, especially the past.

Flashback

38 years ago

"I am pregnant."- Mary Goran said to Mikael as she met him in the Grill, a couple of months after she broke it off with him.

Mikael smiled taking hold of the woman's hand warmly- "Oh, this is so- wonderful."

"Is it?"- Mary said-"I don't know. I- don't know what to do."

"I love you, Mary. And I am ready to do anything. "

"How can you say this? You have a two- year old son. Your family needs you. This not right, whatever we feel. It just is not. I don't know why I have even called you."

"Because you love me, and I love you. And, I know that I have a young family and- oh, I wish I have met you before."

"I wish so many things- and- oh, I am sorry that I- came here."

Mary now started crying. She was completely overwhelmed with the situation.

"We will figure something out."- Mikael tried to comfort her.

Mary abruptly pulled herself together, and walked out of the diner.

Mikael was an emotional wreck after having found out about Mary being pregnant with his child. And he had a family, a wife, he had married, so two families could become even bigger. His father-in-law, who was Virginia stat senator at the time, made sure that Mary stayed with her husband, and Mikael never divorced Esther.

¤¤¤

A few days later

Y/N's day started in the ER, and a colleague now confronting her about the Joel gossip.

"There was a bet on which intern Joel will sleep with first."

Y/N looked at her fellow intern furiously-

"What??? This is disgusting!"

"I know. It's totally lame."- Sam said.

"Who was it?"- Y/N now demanded to know.

"Y/N, I know it is completely out of order. But-"

"I want to know."- Y/N was not letting it go.

"I didn't want to stir shit."- Sam tried to calm Y/N down.

"Tell me!"- Y/N sifted anger making her chestnut eyes darken.

"Brad."- Sam now said.

"Right."- Y/N said and they both now went to take care of the patients, but as she had a break, Y/N went to find the young resident. And confronted him about it in front of the whole cafeteria.

She got some dollar bills out and said-

"How much is a bet it for an ass of the year?

The young resident looked at her astonished but it was clear that she had found out about the bet on Joel and the female interns. He started muttering something but Y/N just continued-

"Joel is flawed on so many levels, yes. He made huge mistakes.But unlike you, he is a good and warm person, and you are a sorry excuse for a human being!"

The whole cafeteria now applauded her. She now turned around and walked out of the place. 

🎃 That night, at home, as she went through a few case studies, Y/N made herself some cocoa and sat down on the bay window. Now there was again this one person on her mind, wondering how he was doing. No matter how much she tried not to feel anything more than just friendship towards Joel, her heart didn’t seem to want to listen to her. She looked out in the night, drawing a deep breath and then went back to the case studied.

A few days later

Caroline was saying bye to Y/N,  as she pulled a night shift and Elena just got in the hospital and already had her hands full with a presentation she was given to work on. And as she was waving Caroline off, her eyes now caught a smiling Rock Star of Orthopaedics. 

"Hey"- Joel greeted Elena and Caroline as he came up to them.

Caroline greeted him back and excused herself and left them to catch up.

"Hey"- Y/N said with a little mental gulp-"so, how was New Zealand?"

"Good. Actually really good."- Joel said-"sorry- I just left. After I talked to the Chief of staff, it was kind of a spur of the moment thing. I needed to - just go. Change the scenery, you know, after everything that -"

"Yeah, I do."- Y/N said and then there was a moment when they both went quiet and Y/N now tried to find to ask something more, and as she wanted to ask how his father was, Joel got a small box out of his bag handing it clumsily to her saying-

"Here. A happy belated - something."

"Oh"- Y/N exclaimed surprised. She opened it and it was a very unusual pendant she had seen.

"This is koru. It's Maori.”-Joel explained clumsily-”Symbolizes awakening, fresh beginnings, rebirth. It's kind of what you did for me the other night. And so I- well- "

Y/N looked at him with a small smile curling up on her lips and slipped quite an emotional thank you. Now the kiss on the cheek made sense. It was a thank you. He could see that she was really moved by the gift.

"In the last couple of days- and - well already on the plane-  I had so much time to think. About everything."- Joel now said-"and - well- "- he was suddenly terribly nervous again. He smiled somewhat nervously and said -"Later? Drink? Rousseau's?"

"Yes. See you there."- Y/N said.

"Ok."- Joel said. 

Y/N looked at the pendant and her heart and head were now more than ever in total confusion, but Joel's wasn't far behind either. He was nervous. He had never been nervous before. Something happened. Could he be in love with her? He just knew that she didn't leave his mind, all the time he was away. 

“Around 8?”- Y/N said .

“Yeah.”- Joel said and now gestured towards the elevator.

Y/N nodded and both then went to whatever was next on the agenda for the day.

¤

As Y/N called Caroline later to tell her that she kind of has this non-date thing, the blonde went now all in what-are-you-going-to-wear, what-will-do-with-your-hair, and Y/N answered simply that she had no plans to dress up.

“It’s only a drink. There is nothing to it, really”

“Nothing? Are you serious? He bought you jewellery!”- Caroline said with a duh voice.

“It’s a thank you thing”- Y/N said-”for being there and listening to him- and that is all”

“Right - tell yourself that. Do what you want.Ok. I’m going back to sleep cuz that double shift killed me.”- Caroline said yawning and hung up.

Y/N went off to her locker, to change. As they never knew how long they would stay in the hospital, she always had a couple of T-shirts and sweaters ready, as well as a pair of jeans. Casual was her style since - well, always. Now, having changed, she put her boots on and leather jacket on. She didn’t bother about the hair at all. She simply undid the pun and combed it a bit. This was not really a date, and she was not Cinderella. Just an intern. And she was meeting a friend for a drink. 

Since, there was still more than an hour till Joel finished his shift, Y/N called Bonnie and met up with her. Since Caroline was not available to listen to her analysing every detail of her heart, Bonnie was her other bestie, who never minded being there for her. Bonnie had a lot to discuss as well, as the night of the birthday lip sync birthday thing, the chemist also went down the line as he friends and hooked up with Kol Mikaelson.

But she now let Y/N talk first.

"Is this a gift wrapped up as a thank you or am I imagining something more? Look, how beautiful it is."- Y/N showed her friend Joel's gift and the meaning behind it.

"I think a thank you and something more is wrapped in it."- Bonnie said.

"You think? I don't know why I am going mad here over it? I can't start anything with him."

"You think he wants to start something?"- Bonnie questioned.

"Knowing him, not really. And then it will be a kind of a rebound thing, although it is not really that."- Y/N said sighing a bit.

"You are overanalyzing everything. Which something you totally do, and then don't listen to your head."- Bonnie reminded Y/N of her past mistakes.

"Caroline said that I am doing again the same thing I did with Kai."- Y/N said.

"Believing that you can change him because you loved him?!"- Bonnie stated.

"Yeah. Huh- but it feels like- it isn't so- like - I didn't know."

"He needs to want to change and break away from his past behaviour."- Bonnie said.

"I think that this thing with this guy dying shook him to the ground."- Y/N said.

"This is some life changing moment."- Bonnie said.

"He said that he felt like he died, like something broke inside of him."- Y/N remembered her and Joel's conversation the night before he left for New Zealand.

"What about Alex and him? There is also the kid."- Bonnie reminded Y/N.

Y/N now told her friends that Alex had talked to her, as the surgeon had presumed that Joel and Y/N had already started something.

"Can things be even more complicated?"- Elena said-"You know what is mad actually? He might not want to be anything but friends, which I totally get. The last thing he needs is a new relationship. I need to let this go."

"Yeah, you need to let this go."- Bonnie said.

Elena nodded, and her heart tried so hard to dismiss the idea that Joel may not have feelings for her.

"But you won't be able to let this go?"- Bonnie then said as she saw her friend play with the pendant all huffed up.

"Why does it have to be so complicated? I always fall for the wrong guy!"

"What you need to do is actually find out how he feels. And if he doesn't feel like you feel, or anything remotely, then you will have to let this go."- Bonnie said and with that their conversation ended as Joel now walked in the bar.

Bonnie, who was usually a very subtle person, this time did the opposite. As Joel got to the table they were sitting at, she greeted him and then made an excuse that she had to go.

"I hope it is not because of me."- Joel said.

"No. She was like leaving the last half hour, but I just kept her talking about - the upcoming charity thing she is busy with."- Y/N fibbed a little.

"Right. You want the same?"- he now asked about the drink.

"I am fine. I am kind of hungry, one more cocktail would completely knock me out."

"Well, do you want to go and grab something? I am kind of hungry, too."- Joel said.

"Yeah- cuz it’s been a long day. You know Sophie's Food Heaven?"- Y/N asked.

"Of course."- Joel said-"comfort food 100%. Whenever I eat there, I have to go to the gym straight after."

"So true. Caroline and I went there the other day and we were so full that we thought we wouldn't need to eat the next two days."- Y/N said grabbing her bag now-"so you go there a lot?"

"It's a place I used to go with my mom, especially when she would do long shifts at the hospital."- Joel said.

"Hospital?"- Y/N was puzzled.

"Didn't I tell you that she was a nurse?"

"No. But it makes perfect sense. Did she meet your dad there?"- Y/N asked.

"No. They met at the Whitmore Medical School. They both were teaching there at the time. He was working at the Charlottesville Memorial."- Joel explained and then said-"Your car? My car?"

"Ahm- I'll go with mine. Meet you there."- Y/N said.

"Ok."- Joel said and then went to his car.

¤

Elsewhere

Mikaelson Mansion

Klaus went to his parent's house to meet up with Camille, to try and talk to her about the divorce settlement.

"I don't want a divorce. I stopped the proceedings."- Camille said-"I want us to go to marriage counseling. I want to save our marriage."

Klaus shook with his head in negation.

"Why?"- she continued-"Why would you not try? We loved each other. We - both made a mistake. We just fell in a rut and - then things happened. You slept with her and then I slept with Marcel, just to get back at you. But I didn't stop loving you. We can find the way out of this."

"Yes. There is a way out of this and -"- Klaus stopped there for a second looking at his wife. She was a dear, sweet woman. Loving. And he hated hurting her. He hated the whole situation, but he had to now say it.

"I- don't love you anymore. I am so sorry- but it is- the truth. I should have told you that already in New Orleans, and save you from all this -"

Before he could finish the sentence, Camille slapped him.

Whether the slap was justified or not, Camille was at the end with her nerves and the last words provocated her now shouting at him to get out.

Klaus made a little sigh and walked out of the room, stumbling on his sister Freya as he walked down the long corridor.

"Klaus?"- Freya ran after her brother.

He ignored her and now, as he got out of the Mansion got into his car, put his foot on the accelerator, driving off like a lightning.

😍

In Sophie's Food Heaven Diner

Sophie Deveraux, who knew Joel since he was a kid, watched Joel and Y/N for a little while as they were chatting away quite happy and relaxed. Very rarely did she see him with a woman there. The waiter got the desert and as he walked to their table, Sophie now went with him.

"Hi. I hope the steak was good."- Sophie said.

"Perfect."- Joel said.

"Absolutely great."- Y/N complimented the Chef.

"She is the Chef/owner. Sophie Deveraux."- Joel said introducing her to Y/N.

"Nice to meet you."- Y/N said.

"Nice to meet you, too."- Sophie said-"so good to finally meet Joel's girlfriend."

"I am- we are not-"- Y/N said.

Joel was like what the heck Soph. And knowing how straight forward she was she now said-

"You could have fooled me. This dinner is on the house. Enjoy."

"What?"- Y/Na was beyond surprised.

"We go way back."- Joel said and explained that he knew Sophie when they were kids- and now told Y/N something that kind of made him somewhat blush-

"She was the first girl I kissed and - yeah. And she just has this thing- I am allowed to  comment."

"And a free meal."- Y/N said-"so you are friends with a girl."

"Ha?"- Joel looked at Y/N a bit gone out.

"Ah, sorry. It was just- ok, I heard you say that you don't believe that man and women can be friends.Sorry."

"Well, it is something I said- and something- I so regret saying - I am really pathetic, aren’t I? So lame. I've said and done so many stupid things. "

"Hey. I didn't want to make you feel bad."

"You didn't."- Joel said-"I went and talked to a friend of mine, also from my childhood. She is Maori. She is a doctor, but a spiritual woman too. We talked about stuff and - you know- Selina's husband -and everything that had happened recently "

"Joel-”- Y/N said in a dear manner.

"I am not religious. I am a surgeon, and I know how the body works. She talked about the soul and that I have to connect with it again. Get to my wairua. She said also that I don't believe in love. That I don't know how to be loved, and give love, and that I-  But that I will know it only then when I find my soul. Huh. Here we are with that stuff - again."- Joel now sighed-”I so didn’t want this evening to be like a therapy session.”

"It's ok. It’ s good to talk ”- Y/N reassured the dishy surgeon.

"Thank you, but I - don't want to think that I am - using you as a shoulder to- cry on. Because this is the last thing that I want."

"It's ok to talk. You are not weak if you have to talk about heavy stuff. It's human."- Y/N said.

Joel smiled a little now and added- "Did someone ever tell you that you have that kind of bold bossy thing - in your eyes-"

"Yeah."- Y/N said chuckling a bit-"since I was born. Although Caroline is far bossier and more ambitious. She was twice elected as the President of the class."

“Oh, I can imagine. They way she is, soon she will take over as Chief of staff before she gets to be Resident.”- Joel said remembering the way Caroline sorted a situation out among her fellow interns and Residents.

“Well, you would not believe that once upon a time she was a really shy and insecure girl”

“I can’t see that.”- Joel said and now took a scoop of the apple pie and ice- cream.

The conversation now swayed to the her and Caroline’s High School days and all their shenanigans. 

A little later, as they got out of the Diner, with Joel finally convincing Sophie to let him pay the bill, they each stood for a second before they got into their respective cars-

"This was like- one of the best - dinner thing I had in a long time."- Joel said.

"Good. Next time it is on me."- Y/N said-"Or maybe we should let Sophie buy us a meal."- she referred to the silly negotiations he and Sophie had a few minutes ago.

"Yeah. Why the hell not. Then we will get all of the menu."

"Ok. Thanks for this- food."- Y/N said with a tiny smile curling up on her lips. 

"You’re welcome."- Joel said.

And then there was awkwardness. And to cut it, Y/N now said- "Tomorrow"

"Yeah, tomorrow."

Y/N nodded a little with a smile and went into her car.

Joel got into his car and took a moment, watching her drive off. He smiled a little as his emotions danced up the way they had never done before. And he so wanted to go after her and tell her that she freed his soul. How? When? He could not pinpoint it. Like it mattered. Everything with her was so effortless and made him feel good and all so fuzzy inside.  He now started the engine and .

A little later, he walked to her apartment and rang the bell.

Y/N opened the door and was surprised to see him there.

"Ahm, hey- did you forget something?"

"Yes, kind of- hm"- Joel smiled nervoulsy-"I forgot- well, to tell you that- tonight was kind of amazing- and - God- this is- I - just-"

His heart wanted to actually say this-”Before all I heard was silence,Life was stringing me along, Then you came and you cut me loose, And now  I'm dancin' on to your heartbeat, And when you're gone, I feel incomplete,So if you want the truth-I just wanna be part of your symphony”

"What?"- Y/N felt like her heart was going to burst as all her predictions and all she had felt now were coming to light.

Joel moved clumsily with his head aside and now said-"I think that I-m in love with you."

Y/N now smiled at him and replied-

"I think that I - am, too."

Joel now was kind of stunned, looking at her seriousl, emotions flying high,  and slipped a little-

"You are?"

Y/N nodded.

He now entered the apartment and kissed her.

Caroline now stormed out of her room and cut in the middle of the Y/N and Joel’s kiss saying-

"Klaus - has been in a car accident. It's not good."

“What? How? When?”- both Joel and Y/N now looked at Caroline, who looked for her car keys.

Joel’s pager now went off, and then said to Y/N and Caroline-

“I’ll drive”

Caroline nodded and all three of them rushed to the hospital.

 __________

[orbemnews]

Air pollution can lead to irreversible blindness, dire new study reveals Air pollution in Europe is a major problem, with a report last year from the European Environment Agency (EEA) linking it to more than 400,000 deaths in the EU and the UK. While this information had already been established, new research has exposed even more dangers of air pollution. Research from University College London (UCL) found those who live in highly polluted areas are eight percent more likely to suffer from irreversible sight loss, known as age-related macular degeneration (AMD). AMD is the leading cause of sight-loss among people over 50 in wealthy countries. The number of sufferers across the globe is expected to reach 300 million by 2040. Air pollution had already been linked to an increase in the risk of Alzheimer’s disease, Parkinson’s disease, stroke, and glaucoma. However, scientists wanted to establish a link between air pollution and AMD. To do so, they analysed data of 115,954 UK Biobank study participants aged 40 to 69 with no eye problems at the start of this study in 2006. Participants were asked to disclose any official diagnosis of AMD or “structural changes in the thickness and/or numbers of light receptors in the retina – indicative of AMD”. They then compared the data with information from the EU Environmental Determinants of Health Project, which looks at pollution levels of particulate matter (PM2.5), nitrogen dioxide (NO2), and nitrogen oxides (NOx). The team found those in higher polluted areas were eight percent more likely to be diagnosed with AMD, according to the findings published in the British Journal of Ophthalmology. Lead author Professor Paul Foster, from UCL Institute of Ophthalmology, said: “Here we have identified yet another health risk posed by air pollution, strengthening the evidence that improving the air we breathe should be a key public health priority. “Our findings suggest that living in an area with polluted air, particularly fine particulate matter or combustion-related particles that come from road traffic, could contribute to eye disease. “Even relatively low exposure to air pollution appears to impact the risk of AMD, suggesting that air pollution is an important modifiable risk factor affecting risk of eye disease for a very large number of people.” Dr Sharon Chua, of the same institute, who was the paper’s first author, added: “Higher exposure to air pollution was also associated with structural features of AMD. “This may indicate that higher levels of air pollution may cause the cells to be more vulnerable to adverse changes and increase the risk of AMD.” if(typeof utag_data.ads.fb_pixel!=="undefined"&&utag_data.ads.fb_pixel==!0)!function(f,b,e,v,n,t,s)if(f.fbq)return;n=f.fbq=function()n.callMethod?n.callMethod.apply(n,arguments):n.queue.push(arguments);if(!f._fbq)f._fbq=n;n.push=n;n.loaded=!0;n.version='2.0';n.queue=[];t=b.createElement(e);t.async=!0;t.src=v;s=b.getElementsByTagName(e)[0];s.parentNode.insertBefore(t,s)(window,document,'script','https://connect.facebook.net/en_US/fbevents.js');fbq('init','568781449942811');fbq('track','PageView') Source link Orbem News #Air #blindness #dire #irreversible #lead #Pollution #Reveals #Study

[airmanisr]

Hawker Siddeley Gnat T.1 ‘XR977’ by Alan Wilson Via Flickr: c/n FL574 Built 1964 and delivered to No4 Flying Training School (FTS) at RAF Valley in Anglesey. She was transferred to the Central Flying School at RAF Kemble in March 1976 and by April had joined the ‘Red Arrows’ team as ‘Red 3’. The ‘Red Arrows’ Gnats were replaced by Hawks during 1979 and XR977 was retired to No2 School of Technical Training at Cosford. She was transferred to the Museum collection in 1982 and remained on display there until moving to Hendon in December 2017. She is on display in Hangar 1 as part of the “RAF First 100 Years” exhibition. RAF Museum London. Hendon, Greater London, UK 3rd October 2020

[vsplusonline]

कोरोना: इंसानी हलचल कम होने का चीन, इटली और भारत की आबोहवा पर पड़ा कैसा असर? - Covid19 satellite data suggest no large scale decrease in emissions in india

New Post has been published on https://apzweb.com/%e0%a4%95%e0%a5%8b%e0%a4%b0%e0%a5%8b%e0%a4%a8%e0%a4%be-%e0%a4%87%e0%a4%82%e0%a4%b8%e0%a4%be%e0%a4%a8%e0%a5%80-%e0%a4%b9%e0%a4%b2%e0%a4%9a%e0%a4%b2-%e0%a4%95%e0%a4%ae-%e0%a4%b9%e0%a5%8b%e0%a4%a8/

कोरोना: इंसानी हलचल कम होने का चीन, इटली और भारत की आबोहवा पर पड़ा कैसा असर? - Covid19 satellite data suggest no large scale decrease in emissions in india

भारत ने वायरस के फैलाव को रोकने के लिए कई कदम उठाए

केंद्र और राज्य सरकारों ने कई एडवाइजरी जारी की हैं

नोवेल कोरोना वायरस (COVID-19) के फैलाव को रोकने के लिए दुनिया के कई देश अभूतपूर्व कदम उठाने को मजबूर हुए हैं. ऐसा ही एक कदम है शहरों को पूरी तरह लॉक-डाउन करना. चीन और इटली को स्थिति के बेकाबू हो जाने के बाद ये अतिवादी रास्ता अपनाना पड़ा. ऐसा कोई निश्चित तरीका नहीं है, जिससे मानव गतिविधियों को सीमित किए जाने के असर को मापा जा सके लेकिन इसके वातावरण पर प्रभाव को कु�� हद तक नापा जा सकता है.

वैज्ञानिकों ने एक निश्चित पैटर्न को पकड़ा है जो नाइट्रोजन डायऑक्साइड (NO2) के घटे हुए स्तर को दर्शाता है. पहले चीन और अब इटली में बड़े पैमाने पर लोगों को घरों में या अन्यत्र पृथक रखे जाने की वजह से यहां मान�� गतिविधियां सीमित होने पर वातावरण में NO2 की कम मात्रा मापी गई. दरअसल नाइट्रोजन ऑक्साइड मानव संचालित गतिविधियों जैसे कि मोटर वाहन, ऊर्जा संयंत्र और औद्योगिक इकाइयों की वजह से वातावरण में उत्सर्जित होती है.

ये भी पढ़ें- कोरोना को हराने की तैयारी, MNC से गुरुग्राम प्रशासन बोला- Work From Home

NASA और यूरोपीय स्पेस एजेंसी (ESA) , दोनों का मानना है कि NO2 का स्तर घटना सीधे तौर पर इन क्षेत्रों में मशीनों से जुड़ी गतिविधियों का प्रभावी ढंग से कम होना है.

भारत की क्या स्थिति है?

भारत ने कोरोना वायरस के फैलाव को रोकने के लिए कई कदम उठाए हैं. केंद्र और राज्य सरकारों ने इस संबंध में कई एडवाइजरी जारी की हैं. हर मुमकिन कोशिश की जा रही है कि वायरस के संक्रमण को कम से कम किया जा सके. अधिकतर राज्यों में स्कूल कॉलेज, सिनेमा हाल बंद कर दिए गए हैं.

ये भी पढ़ें- कोरोना मरीज ने किया था भुवनेश्वर एक्सप्रेस में सफर, संपर्क में आए थे 129 यात्री

खेल से जुड़े आयोजनों को भी रद्द कर दिया गया है. मंगलवार को महाराष्ट्र में सरकारी दफ्तर भी एक हफ्ते के लिए बंद करने का एलान किया गया. घरेलू यात्राओं और औद्योगिक सेक्टर के लिए कोई सख्त आदेश नहीं दिए गए हैं लेकिन नागरिकों को सलाह दी गई है कि वे यात्राओं और बैठकों से बचें.

यहां तक कि प्रधानमंत्री भी लोगों को घर से ही काम करने के लिए प्रोत्साहित कर रहे हैं. हालांकि यूरोपीय स्पेस एजेंसी का सैटेलाइट डेटा बताता है कि भारत में NO2 के स्तर में मामूली ही कमी आई है. ये डेटा 17 फरवरी से 16 मार्च के बीच जमा किया गया. यानी साफ है कि भारत में तमाम एडवाइजरी के बावजूद आउटडोर मानव गतिविधियां इस स्तर पर कम नहीं हुई कि उनकी वातावरण पर कोई छाप देखी जा सके.

हालांकि कोरोना वायरस को लेकर भारत में चीन या यूरोप जैसी स्थिति नहीं है. चीन और यूरोप की अमेरिका और इंग्लैंड की सरकारों के साथ इसलिए आलोचना की जा रही है कि उन्होंने समय रहते पहले सख्त कदम क्यों नहीं उठाए. कोरोना वायरस के फैलाव की बात की जाए तो वैश्विक विज्ञान समुदाय में आम सहमति है कि कोई भी कदम पर्याप्त नहीं है और ऐसे में एहतियाती उपाय किए जाना ही अधिक कारगर रहता है.

दुनिया भर के विशेषज्ञ वायरस के नए क्षेत्रों में फैलाव को रोकने के लिए अधिक कठोर कदम उठाने की सलाह दे रहे है. बड़े पैमाने पर लोगों को अलग करना और बड़ी संख्या में कहीं जुटने पर रोक लगाने से प्रभावी नतीजे सामने आए हैं.

आजतक के नए ऐप से अपने फोन पर पाएं रियल टाइम अलर्ट और सभी खबरें. डाउनलोड करें

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Lupine Publishers|An Efficient Protocol for the One Pot Synthesis of Pyranopyrazoles in Aqueous Medium using Triethanolamine as a Catalyst

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Abstract

Triethanolamine is an efficient and green catalyst for the synthesis of 6-amino-1, 4-dihydro-4-substituted-3-methylpyrano-[2, 3-c] pyrazole-5-carbonitrile in aqueous medium reflux conditions. The procedure is easier, eco friendly, simple with easy workup affording good yield of the corresponding products.

Keywords: Multi component reaction, Water media, Pyranopyrazole, Catalyst, Triethanolamine

Introduction

The present scenario for organic synthesis indicates the crave for green and economical synthesis of organic compounds. One of it is multi component synthesis. Strecker’s synthesis for amino acids was the first report on multi component reaction [1]. Last few decades show large development in it. The main aim of such reactions is to fasten the reaction rate by reducing number of steps involved and eventually increase the yield of reaction. In this context to achieve great efficiency catalysts are employed. Catalysts such as Nano α-Al2O3 supported ammonium dihydrogenphosphate [2], tungstate sulfuric acid [3], Fe3-xTixO4@SO3H nanoparticles [4], nano-titania sulfuric acid (15-nm TSA) [5], nanostructured MgO [6], H14[NAP5W30O110] [7] and ZnO Nanoparticles [8].

Figure 1:  

Organic catalysts such as Triethylamine [9] DABCO [10], Trishydroxymethyl aminomethane [11] are also reported in various organic transformations. Triethanolamine contains basic tertiary amine and primary alcoholic part (Figure 1).

It is used for activation of both CO2 and epoxides to convert them in to cyclic carbonates [12]. It is also reported as a legend for copper catalyzed hydroxylation of aryl halides in aqueous medium [13]. It is used as aqueous solvent for controllable preparation of ZnO nano flowers in sol gel technique [14]. Its aqueous solution is reported as electrolyte in CO2 Photo electro-conversion catalyzed by Cu- Doped Graphene-Titania Catalyst [15]. Also it is found to increase the rate of oxidation of mesitylene catalyzed by cobalt bromide [16]. It is used as sacrificial electron donor in photocatalytic system [17]. Furthermore; it improved the catalytic performance of CuBr/ PMDETA in the atom transfer radical polymerization [18]. It is also used as phase transfer catalyst for synthesis of 1-(arylsulfonyl) aryl/heterylmethanes [19]. It is used as medium for synthesis of 3-substituted coumarins using L-proline as a catalyst [20]. It is reported as catalyst in 10 mol% for synthesis of 2-amino-3-cyano- 4H-pyran derivatives under ultrasound irradiation at 600C [21].

Synthesis of substituted pyrano-[2,3-d]-pyrimidines via one-pot three-component condensation of aromatic aldehydes, malononitrile and barbituric acid or 2-thiobarbituric acid using trace amounts of ionic liquid (choline chloride.ZnCl2) and triethanolamine (0.1Mol%) at 75°C with stirring and under ultrasound irradiation [22] is also reported in literature. Herein we successfully attempted a fast and simple protocol for the synthesis of 6-amino-1,4-dihydro-4-substituted-3-methylpyrano [2,3-c]- pyrazole-5-carbonitrile by the one pot three component reaction of aromatic aldehyde, malononitrile and 3-methyl-1H-pyrazol-5(4H)- one using triethanolamine as a catalyst [23].

Results and Discussion

To explore the synthetic application of triethanolamine, in the present work we report the catalytic facet of it for the synthesis of heterocyclic compounds bearing pyrazole skeleton. To optimize the reaction conditions, we chose anisaldehyde as the prototype. Initially, 10mol% of triethanolamine was taken for solvent free reaction at room temperature. But the reaction afforded a low yield of the product after 2 hour stirring. Then we used 10ml of water for room temperature stirring [24]. After 2 hours stirring it gave 62% of yield. The yield of reaction gets drastically changed on increasing temperature. At 900C we got 85% of yield of the product. When 20mol% of triethanolamine was used then we got 92% of yield at 900C in 10 ml water. Other solvents were also studied expecting better yield but other than ethanol and water we got poor yields (Table 1). Further increase of temperature and amount of triethanolamine did not improve yield significantly (Table 1). After optimizing the reaction conditions, differently substituted aldehydes with electron donating as well as electron withdrawing groups were reacted to examine the feasibility of this catalytic reaction (Scheme 1).

Table 1:  Optimization of reaction conditions for the model reaction (Scheme)*

Almost all aldehydes bearing various substituents such as –Cl, F, -NO2, -OMe etc afforded good yield of the corresponding products. All the synthesized compounds showed sharp peaks at 3410, 3356cm- 1(-NH2) and 2190cm-1(-CN) in IR spectra which supports for the formation of pyranopyrazole. The formed products being insoluble in water were easy to separate from the aqueous medium by simple filtration. The reason for catalytic activity of triethanolamine is it’s solubility in aqueous medium and basic nature. Products are simply purified by re crystallization with ethanol. Thus the protocol described herein is efficient for the synthesis of pyrazopyrazoles which do not need purification by column chromatography.

Model reaction* for anisaldehyde (2mmol), malononitrile (2mmol) and 3-methyl-1H-pyrazol-5(4H)-one (2mmol) using the above cited conditions @Isolated yield.

Scheme 1:  Model reaction for the synthesis of pyranopyrazoles.

Experimental

Melting points were recorded in open capillaries and were uncorrected. Progress of reaction was monitored by TLC (30% of ethyl acetate: n-hexane). IR spectra were taken by KBr disc on Shimadzu IR Affinity 1 spectrophotometer [1]. H NMR spectra were recorded on a Varian 400MHz spectrophotometer in the specified solvents. Chemical shifts were expressed in 𝛿ppm relative to TMS. Mass spectra were recorded on a Macro mass spectrometer (Waters) by electro spray method (ES).

General method for the synthesis of 6-amino-1, 4-dihydro- 4-substituted-3-methylpyrano-[2,3-C]-pyrazole- 5-carbonitrile

To a stirred mixture of aromatic aldehyde (2mmol), malononitrile (2mmol) and triethanolamine (20mol %) in 10ml of water, 3-methyl-1H-pyrazol-5(4H)-one (2mmol) was added. The resulting mixture was stirred and heated at 900C for appropriate reaction time (Table 2). After completion of reaction, the reaction mixture was cooled, filtered off the residue as the crude product which was further purified by re crystallization form ethanol (Scheme 2).

Scheme 2:  General scheme for the one pot three component synthesis of pyranopyazoles using triethanolamine catalyst.

Table 2:  Yield and reaction time of various pyranopyrazoles using triethanolamine.

Representative Spectral Data

6-Amino-1,4-dihydro-4-(4-methoxyphenyl)-3-methylpyrano[ 2,3-c]pyrazole-5-carbonitrile (4a)

White solid, [1]H NMR (400 MHz, DMSO-d6): 𝛿 ppm 12.08 (s, 1H), 6.87-7.23 (m, 4H), 6.81 (bs, 2H), 4.45 (s, 1H), 3.78 (s, 3H), 1.81 (s, 3H); IR (KBr) cm-1: 3425, 3128, 2928, 2200, 1597, 1153, 1203; ES-MS m/z: 283.2 (M+1)+.

6-Amino-2,4-dihydro-3-methyl-4-phenylpyrano[2,3-c] pyrazole- 5-carbonitrile (4e)

White solid, M.P. 245-246 0C; 1H NMR (400 MHz, DMSO-d6) : 𝛿 ppm 12.10 (s, 1H), 7.10-7.40 (m, 5H), 6.85 (s, bs, 2H), 4.60 (s, 1H), 1.78 (s, 3H); IR (KBr) cm−1 : 3410, 3356, 3167, 2990, 1646, 1596, 1399, 1276, 870; ES-MS m/z: 253 (M + 1) +.

6 - A m i n o - 4 - ( 4 - c h l o r o p h e n y l ) - 3 - m e t h y l - 2 , 4 - dihydropyrano[2,3-c]pyrazole-5-carbonitrile (4g)

Off-white solid, M.P. 230-2320C; 1H NMR (400 MHz, DMSO-d6): 𝛿 ppm 12.15 (s, 1H), 7.10–7.40 (m, 4H), 6.95 (s, bs, 2H), 4.63 (s, 1H), 1.80 (s, 3H); IR (KBr) cm−1 : 3478, 3035, 2985, 2193, 1647, 1596, 1398, 1284, 870; ES-MS m/z: 287 (M + 1) +.

6-Amino-4-(4-N, N-dimethylaminophenyl)-3-methyl-2, 4-dihydropyrano[2, 3-c]pyrazole-5-carbonitrile (4j)

Yellow solid, M.P. 234-235 0C; 1H NMR (400 MHz, DMSO-d6): 𝛿 ppm 12.10 (s, 1H), 6.70-7.15 (m, 4H); 6.55 (s, bs, 2H), 4.40 (s, 1H); 2.85 (s, 6H), 1.78 (s, 3H); IR (KBr) cm−1 : 3385, 3172, 2957, 2189, 1644, 1601, 1397, 1279, 868; ES-MS m/z: 296 (M + 1) +.

Conclusion

In summary, we have developed an efficient protocol for the synthesis of pyranopyrazoles by a simple method using a catalytic amount of triethanol amine. Herein; not only the yield of reaction is improved but also the reaction time is reduced. The workup of the reaction is very simple which make it easier to isolate the product.

Acknowledgement

The authors are thankful to The Principal, Vinayakrao Patil Mahavidyalaya, Vaijapur for providing laboratory facilities and The Director, SAIF, Chandigarh for NMR and Mass analysis.

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