#isomer spoilers

[hydrocarbon-extractor]

semi-important stuff & methodology

read if you want

or don't

also a cool list of everything found so far...

forenote:

unfortunately, not all posts can produce a hydrocarbon upon analysis. this can be for many reasons. the most frequent, however, is an odd number of hydrogen (h) atoms¹, so if your post/ask doesn't get a response, this may be why.

i also try to avoid longer posts as there are so many combinations possible that many are unstable or just not documented.

others may have multiple possible structures. i try to minimise complexity (again, for readability), so multiple structures will only be shown for posts containing 6 or fewer carbon atoms.

this is also where i stop caring about set completion (see list at end).

methodology:

first, a post is stripped of all letters other than 'c' and 'h', leaving punctuation and emojis for clarity.

secondly, points in the post that must remain constant are located (ie, a CH3 group at the start/end), then i work forwards/backwards from there.

as far as i am concerned, any adjacent hydrogens are fair game (ie, ethene could be expressed as hchhch, chhhhc, hhcchh... but not cchhhh), so they are matched up with carbons to maintain 4 bonds per C atom.

most hydrocarbons have a cyclic isomer, too; so if it has one that is accessible from the post, i will usually include it. sometimes i can only make the cyclic isomer, so the linear one is excluded.

there may also be multiple linear/cyclic isomers, so as stated prior, these will only be included if there are less than or equal to 6 carbon atoms.

lastly, it is double-checked against online databases to ensure it does indeed exist, and i am not stupid (spoiler, i am).

1: while i am aware radical and ionic substances fit this description, this is a dumb gimmick blog, and i am trying to maintain as much readability for the average reader as possible.

end of technical bit

despite this blog being a parody of the usa in many ways, it does not share several of the various governments' opinions, and is intended to be a safe space for everyone.

they/them pronouns please

list of previously identified hydrocarbons by number of carbons, molar mass, and bond complexity²:

C₀ 1/1 ☆

002 - dihydrogen

C₁ 1/1 ☆

016 - methane

C₂ 3/3 ☆

026 - ethyne

028 - ethene

030 - ethane

C₃ 7/8

038 - cyclopropadiene

038 -

040 - propadiene

040 - propyne

040 - cyclopropene

042 - propene

042 - cyclopropane

044 - propane

C₄ 6/

050 -

052 - butatriene

052 - cyclobutyne

054 - buta-1,2-diene

054 - buta-1,3-diene

054 - cyclobutene

056 - cyclobutane

058 -

C₅ 3/

064 - pentatetraene

066 - penta-1,2,4-triene

066 - cyclopenta-1,2-diene

072 -

C₆ 4/

074 -

076 - cyclohexa-1,2,3,4-tetraene

080 - hexa-1,2,5-triene

080 - cyclohexa-1,4-diene

086 - hexane

C₇ 1/

092 - cyclohepta-1-ene-3-yne

C₈ 0/

C₉ 0/

C₁₀ 0/

C₁₁ 0/

C₁₂ 2/

166 - dodeca-2,4-diene

166 - cyclododecene

2: all masses are to the nearest integer value, colour coded by number of carbon atoms.

only non-ionic, non-radical hydrocarbons (and dihydrogen because it's funny) are included in sets. complete sets (6 carbons and below) labelled with a star ☆.

only compounds i have been able to locate in databases are included.

[give-fnc-chocolate]

[scarletlotus182]

GOD I LOVE THIS SO MUCH

The character development has been so goddamn strong for the last several events and I could not be more happy.

Like, it doesnt even feel like I'm in the same story the early gfl chapters took place in.

[commander-frostii]

i’m for real going to cry.

you did it, girls.

[all-hail-trudos]

Isomer is over and I'm left with feels. All the moaning I heard made me think this event would be more brutal than Singularity (flashbacks to learning what the hell "gunboats" were, and mastering kiting so I could survive the damned laser tanks). But it was a lot of fun, and the writing alone makes this the best event yet. I really enjoyed it. But then life and work and the stress of both of those got to me, and I didn't actually finish the story or try the ranking mission until today. Which leaves me kinda sad and more depressed.

But overall 10/10. Would watch that heart-warming reunion again.

[danwhobrowses]

ROH Death Before Dishonor 2022 - Quickfire Reaction

It's been another wild month of wrestling, continuing on with ROH's second Khan-era PPV.

A stacked card begets a lot of potential to be a great show, doubly impressive when in the middle of G1 and Summerslam season, but can it top Forbidden Door? Let's see

Spoilers for the Show

Zero Hour

It's a little sad that Colt isn't repping Dark Order anymore but good to see him back in a ring. Same for Anthony Henry, the Workhorsemen are a good tag team well-suited for ROH (even though I must admit I love the Wingmen too)

Match was good for getting the crowd involved, Henry did a lovely piledriver and Frog Splash for two different nearfalls but Cabana powers through

I've heard news about the Trustbusters from some AEW Dark spoilers, but for first impressions: good music, good talent in Slim J, probably gonna do well as weaselly midcard heels until they get some muscle

Eli Isom impressed me a lot more this match than he did in Supercard against Gates of Agony

I dunno who this Prince Nana is but buying TBE seems weird to me, is Tully not gonna be a part of it anymore? Seems like it with them being called The Embassy, maybe Tully will just be with Gresham?

I said it at Supercard and I'll say it again, Cage is best when he's just hossing

Zayne (fresh off of BOSJ), Christian and Deppen did really well too, they built Christian's hot tag really well, Deppen did a lot of workhorsing and Zayne undoubtedly was great

How can you not love Willow? Her music is great too

Nice little blend of technique and power in that match

4 matches in 1 hour, you see that WWE?

Main Card

Kicking off with the world title!? That is bold

Love Claudio's new theme music btw, I wouldn't have minded if all of BCC had classical remixes but I get why Mox sticks with Wild Thing, plus Yoots still has a good theme tune

Gresham didn't come out with Tully though, so wonder what that's about? Regal joins commentary too to enrich us more

Classic story of ligament damage vs power

Gresham has struggled with AEW crowds getting him but GOD he is so clean

CLAUDIO DID IT! HE FINALLY WON A WORLD TITLE!

I appreciate the BCC elbows helped transition to the Ricola Bomb, we pushing that BCC agenda and I am here for it, I think I liked that match more than the ZSJ match

Claudio's joy is also infectious, that's an opener!

Glad to see more Dalton, dude is charismatic for years

This is the first I've seen of the Righteous, their music is unique, they have kinda cult energy with a dash of Big Lebowski, I'd happily see more of them

I enjoyed the match more than I thought tbf, lots of charisma, lots of fun, commentary made me grin too, I had predicted Castle and Boys to win but it surprised me that they went 2 title changes in a row

Garcia still rocking the kangol XD And using the Regal colours

Could we possibly just get Regal on commentary like every title match? He's so joyous but also technical, you learn so much

Production has gone up with the PURE rules UI, timer and the rope break bars

Yoots has a great German Suplex, not Takeshita level but still great

It's a very interesting but valid strategy to see Garcia and Yoots work the ears, you don't see it a lot

I was also glad to hear that there's intent towards Yoot not going for a rope break, because his last few Pure matches have had him be the first to lose a rope break and I always felt that feeling like weakness

Loved the submission swapping relating to JAS and BCC too

That is the best PURE match I've seen so far in the Khan era, if it weren't for Claudio challenging Gresham I would've picked Garcia for this, but I wanted that BCC agenda and I'm getting it, Bryan needs to come back so he's next

Dragon Lee. Lawn Darted RUSH. Through a Table!?

This is pure Penta vs Fenix energy in the best way, both have the same kind of builds and mentality

Seriously, no build, no title, and yet this still was a banger

I wonder if Lee will join La Faccion Ingobernable down the line, because I know RUSH and Andrade are facing the Lucha Bros but I see it going into trios, maybe Andrade taking the All-Atlantic title from PAC

Every American one time or another will call Worcester 'War-chester' XD to be fair us Brits do too but we learn quickly because of Worcestershire Sauce

No surprise that Serena vs Mercedes is extremely technical

Match got a little slow in the middle but it was good, really thought though that Serena would be given her due, she's showed up against Shida, Rosa and Mercedes and the ROH women's title did feel like a good fit for her

Lethal sent Singh and Dutt away which is interesting

Joe pulling a Suzuki look as they go straight at it!

Didn't last long, Singh came back to help Pillmanize Joe's shoulder, match hadn't started yet so fair game. But the ref ejects Singh before ringing the bell, which is clever, didn't eject Dutt though when he brought in a pipe (to feint so Lethal could use the belt)

Crowd have been rabid for this match, I was okay about it, the build and the interferences made me less invested

Woof, Fight for the Fallen ain't messing around; Mox vs RUSH, Swerve vs Sterling & Nese, Danielson returning vs Garcia, good stuff

Surprised Dax didn't wear his 'Fight like an 8 year old' shirt, AEW made them to donate to children's heart charity

The pop for the bell ringing wasn't as loud as last time which was a shame

Jay and Dax went 200 miles an hour there, but it looks like it hurt him a bit since they had him checked by medical, post-show reports say it's precautionary which is fortunate

Doesn't stop his capacity for the hot tag though

After the first fall we got some clever psychology from the Briscoes

Cash has a great hot tag too

The camera is looking for something but it's not quite finding it

Is 2 out of 3 no rules? Because I feel like being hit with a bell is a DQ

Everyone's showing some colour now

It's been a good night for clean looking piledrivers

Ref bump seems to be to give the Briscoes a visual win with the Jay Driller, though FTR also had a visual win with the Big Rig after, maybe a part 3 is in waiting? Iron Man maybe?

They did the Revival vs DIY/American Alpha spot with holding hands during a submission

JESUS! Chekov's table from Lethal/Joe comes back for Cash super back body dropping Mark!

Jay Driller just for 2!

SUPER PILEDRIVER

The finish was great, I think I slightly preferred the Supercard match but gosh that was a great match

Oh sure give me FTR vs BCC, I've got a vein to inject it into

Conclusion

This was a great PPV.

I think I preferred Forbidden Door by an inch, but it has to be on a similar level because ROH didn't suffer so much from abrupt endings and injury, but the match quality for Forbidden Door was slightly higher, but it was better than Supercard overall which is a plus.

The matches were all really good, very happy to see Claudio win a world title finally. Khan booked the PPV strongly and hopefully it pays off for him, I don't see how tv companies wouldn't be considering ROH right now.

Hopefully a new chapter will begin.

Results (and Predictions)

Zero Hour: Colt Cabana def. Anthony Henry (w/JD Drake) - Pinfall via Moonsault Trustbusters (Ari Daivari & Slim J) def. Cheeseburger & Eli Isom - Pinfall on Isom by Daivari via Frog Splash The Embassy (Brian Cage, Kaun & Toa Liona w/ Prince Nana) def Alex Zayne, Blake Christian & Tony Deppen - Pinfall on Deppen by Cage via Dominator/Big Boot combo Willow Nightingale def Allisyn Kay - Pinfall via Gutwrench Powerbomb

Main Card: Claudio Castagnoli (w/William Regal) def. Jonathon Gresham (w/Prince Nana) (c) - Pinfall via Ricola Bomb - TITLE CHANGE!!! Dalton Castle & The Boys def. The Righteous (Vincent, Bateman & Dutch w/ Vita VonStarr) (c) - Pinfall on Bateman by Castle via Bangarang - TITLE CHANGE!! Wheeler Yuta (w/William Regal) (c) def. Daniel Garcia - Pinfall via Seatbelt RUSH (w/José the Assistant) def. Dragon Lee - Pinfall via Bull's Horns Mercedes Martinez (c) def. Serena Deeb - Submission via Dragon Sleeper Stretch Samoa Joe (c) def. Jay Lethal (w/Sonjay Dutt & Satnam Singh) - Submission via Kirifuda Clutch FTR (Cash Wheeler & Dax Harwood) (c) def. The Briscoes (Jay and Mark) [2-1 Falls]

Fall 1: Briscoes (1) def. FTR (0) - Pinfall on Dax by Mark via Doomsday Device

Fall 2: FTR (1) def. Briscoes (1) - Pinfall on Jay by Dax via Big Rig

Fall 3: FTR (2) def. Briscoes (1) - Pinfall on Jay by Dax via Avalanche Piledriver

[anistarrose]

3, 11, and 15 for Some Sunny Day :D

Thanks for the questions! (fic ask meme here!)

3: What’s your favorite line of narration?

I think Chapter 6 is my favorite chapter that I’ve posted so far, and I still really like the intro:

Before Stan even closed his eyes, the bitter taste of the sedative faded into a dull nothingness — an absence of the sense of taste altogether — that confirmed he was dreaming. Images, both remembered and completely invented, flickered in and out of existence around him — most of them forgotten before he could recognize them, lost into the void of half-consciousness…

I think I did a good job setting the tone for the rest of the chapter, and the isomers analogy that follows it is probably my favorite metaphor I’ve written! keep an eye out for that one to come up again :)

11: What do you like best about this fic?

I’m super happy with the ways I’ve brought the lyrics of We’ll Meet Again into the fic. When I first thought of the title, I just thought it would be a clever way to allude to Bill’s return, and didn’t expect to actually feature the song outside of the prologue, but it ended up morphing into this defining feature that dictated a ton of the themes and symbolism - and I can’t imagine it any other way.

15: What did you learn from writing this fic?

I think the experience has been teaching me a lot about allowing the plot and the themes of a story to evolve as I write it. I definitely had an outline when I started, with a beginning, middle, and end that have mostly stayed intact, but a lot of the thematic connections between various events only fell into place one I started writing. The dream bubbles were just tentatively “penciled in” to the outline at first, because I thought they’d be a cool plot twist/way to raise the stakes, but as I wrote, I started to think: “Oh shoot, I can connect this to Stan’s denial! This might actually work super well!”

I was also a ways in (around the time I started to write Ch. 6, I think) when I decided to add an extra scene to the conclusion, which should hopefully make it a more satisfying and cathartic payoff... but that’s getting into spoiler territory, so that’s all I’m saying about that change :) (For now, at least.)

[allykatsart]

(I already posted this, but I wanted to add some information that I thought up of) This is something I'm not actually going to do, not unless I have a lot of time, finish my other projects, and a lot of people want to see it. So think of this is a hypothetical ask blog, with a plot and characters that I've actually thought out. It would take place after fanf 6, so spoiler warnings for that, and all Five Nights at Freddy's games. The basic premise of this ask blog is that the remnant Souls of all the kids or otherwise stuck in animatronics couldn't go on. There was just something that connected them to their bodies. For each soul, the emotional trauma is different, but they all have to let go of whatever it is to move on. When everyone who was released by the fire (in game 6) comes in, only Golden Freddy is left out of all the souls. Since they can't move on, they are stuck in a limbo like place. They can't hurt each other here, but the can receive Isom, or have items made based on their needs or wants. Now, on to the descriptions! First off we have Golden Freddy (Golden), Funtime Foxy (FunFoxy), Funtime Freddy (Fun Fred), Ballora, Baby, Michael Afton (Mike or Mikey), and William Afton (Springstrap). (The names in the the parentheses are what they preferred to be called or what they would be referred to as.) Plot: As I said, I did have an idea for the plot of the ask blog. At first it would be just like any other ask blog you get to ask the characters what you would like, or send them gifts, but eventually the Marionette would appear. (For those of you whoknow the sixth game, you may be wondering why she wasn't there in the first place, and that is because she managed to survive the fire, for just a little longer, before Henry found her and released her to heer.) With her, she would bring the plotXD.  But in seriousness, she harbors a lot of anger, most towards Springtrap, of course, but also some towards Mike. This causes him to try and stay away from the others. Springtrap, meanwhile, has been planning something to try to get him back to life. Baby also joins in on this, both having a desire to become real again. All this time, Springtrap has been very mad at Mike (for basically killing him + undoing all his work on the souls), so when Mike finally start snooping around, he takes this as an opportunity and kidnaps Mike. (Probably promises a lot of bad things to happen once he gets mike back to life.) Mike tries to escape, manages to get some amount of notice before Springstrap recaptures him. However, this does cause some of the others to go looking for him, and they find out about what Springstrap was doing. They manage to save Mike and stop Springstrap.  Unfortunately that's not the end of the trouble, but I've said enough already XD lol. Personalities: -Golden: shy, sad, scared easily, likes to be alone. -Fun Foxy: happy go lucky, quick to assume, loves puns, likes to jumpscare their friends. -Fun Fred: quieter, confused easily, annoyed at jumpscares by Fun foxy, only speaks when he has something to say. -Ballora: helpful, sad, usually in deep thought, takes care/mothers the children -Baby: likes to play around, complains a lot, enjoys a good laugh out if pranks, can sometimes seem cruel, but overall seems ok. -Mike: helpful, tries to make everyone feel comfortable, feels extremely guilty though hides it well, tries to hang out with Baby and Golden a lot, has to sometimes reel in Springtrap when he is being a bit to creepy/sadistic -Springtrap: doesn't interact with the others much, when he does it's in a very creepy way, REALLY good at hiding his true emotions, dad jokes, will do anything to have his family back alive again. And that's all I got XD have a great day.

[latestnews2018-blog]

**Spoiler** Wrestler Debuts At Tonight's ROH TV Tapings

New Post has been published on https://latestnews2018.com/spoiler-wrestler-debuts-at-tonights-roh-tv-tapings/

**Spoiler** Wrestler Debuts At Tonight's ROH TV Tapings

ROH is doing a set of TV tapings tonight at Center Stage in Atlanta, Georgia. At tonight’s show Jeff Cobb made his debut for the company. Cobb showed up after a Top Prospect Tournament match between FR Josie and Eli Isom, taking both guys out, which you can see in the video below.

Scoop 14 – FR Josie vs Eli Isom in a Top Prospect Tournament match. Qualifying match? pic.twitter.com/Exmwqq885u

— Ben Turpen (@BenTurpen) July 21, 2018

Scoop 15 – Jeff Cobb attacks both guys, making his ROH debut. pic.twitter.com/rWZGoXs51v

— Ben Turpen (@BenTurpen) July 21, 2018

Scoop 16 – Jeff Cobb makes his ROH debut pic.twitter.com/eW0XREhdbN

— Ben Turpen (@BenTurpen) July 21, 2018

Cobb is known to Lucha Underground fans as Matanza, but has also worked for Pro Wrestling Guerrilla and New Japan Pro Wrestling. He’s held the Lucha Underground Championship and the PWG World Tag Team Championship (with Matt Riddle).

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[give-fnc-chocolate]

"You can't have a future before you face your past" sounds like one of those lines that doesn't mean anything. Nothing is stopping M4 from just being a family with AR team and ignoring her past, if that's what she wants to do, right?

OGAS in M4's mind is at the very least not the same OGAS helping Mastermind, I assume. Otherwise OGAS would just get the pike node contents from SF.

If K doesn't hold up his end of the bargain I'm gonna let SOP do whatever she wants to him, I swear. Double dealing, two timing, rat bastard!

[give-fnc-chocolate]

On the subject of Nytos being hacked...

I don't trust OGAS in the slightest. And the impression I got was that M4 didn't do anything herself and just assumed OGAS followed through on the promise to hack Nyto.

The reaction of Nimogen and Mercurow when the headband was broken reminded me eerily of the Doctor Who episode when the Cybermen are able to understand what has happened to them. Some of them die on the spot, a lot of them go insane, and one cries at their reflection in the mirror.

I would not be surprised if the headband keeps the Nytos from under control, or stops them from going insane, and for whatever reason OGAS didn't want to tell M4 this.

[scarletlotus182]

THEY'RE SO FUCKING COOL

[scarletlotus182]

This might be my favorite line in the event so far.

T-Dolls are so undeniably human despite being 100 % android

Nyto, despite being made up of human parts are still utterly inhuman

[scarletlotus182]

OKAY

Can I just take this moment to appreciate Ak12's interaction with UKM?

Like this was just a throwaway line but I love Ak12 just going UKM's quirk and how happy it made her. It was really cute!

[scarletlotus182]

An94, please dont talk to strangers

[scarletlotus182]

M4 is officially done dealing with people's shit