#metalcontainer

[billionneuronscurious]

Tin-Can Artwork: Phoenix and Dragon.

(Art from Waste.)

[colorcanmetalpackaging]

Trending Logo Customization Empty Round 2.5oz Scented Candle Tin Box-Color Can The small candle tin is designed to hold scented or unscented candles. It typically features a removable lid for easy access, and the tin is often decorated with vibrant colors or elegant patterns. The metal construction helps retain the fragrance of the candle. If you are in the market for candle tins, just contact us. #candlejar #candleholder #metalcontainer #scentedcandle #custombox You could learn more about us here: https://www.jhtin.com/ Email: noreen@jhtin.com Whatsapp: +86 18029106790

[cuucgardenplanters]

Canister Sets for Kitchen Counter

Kitchen canister sets - These beautiful and inviting food safe metal canister sets will evoke the country farm feel into your kitchen.

👀👀Visit more：www.cuucgardenplanters.com 🙌🙌or contact Cola to get free samples：cola@cuuc-gardenplanters.com

#foodstorage#container#bin#tinbox#lid#handle#pet#storage#metalcontainer

[irrfahrer]

The flowers Ziv told Cayne to pick were small and of a light green colour. When he reached for them the small flower heads closed its petals and leaned away like small scared mice. “Vegetarian? -then pup, you are already the kriffing perfect botanic student. I bow before our perfection-”, playfully she dropped a dramatic little curtsey in all good humor before Cayne. Only to have her broken rip protest promptly, making her shot up straight suddenly and hissing like a snake: “ Kriff, I hate this -”, She grimaced, showing her razorsharp teeth until she had fought down the pain again, and pressed out from between clenched jaws: “You know,I can not even kriffing taste most of the stuff I am growing for people due to my biology, most fruits and vegetables taste like I am licking kriffing sand. Carnivorous tastebuds and all that kriffery, you know. It would make things a lot of kriffing easier for me if I could actually eat what I am already growing, especially when it comes to staying on a plant to terraform alone for months or years, but eh, things are as they kriffing are, so what-kriffing-ever.” She motioned the other to follow her along the narrow beaten paths, while the small flowers thin, little roots curled around Caynes fingers; gently holding to him.

“A song? See, kriffing perfect botanist, as I said it before. Plants kriffing love the vibration a voice leaves in the air, especially when ist melodic on certaine frequenzes. The tree that bears those silver fruits would not have fruits until I would not everyday sit at its foot and kriffing purr for half an hour while leaning against the treetrunk. I would kriffing laugh about it, if it wouldn't be so kriffing annoying. You got the potential, now we only need to fill that head of yours with the pretty little fitting botany facts-”

There was a noise above the glassdome that was the biodoms roof and Zivs head suddenly snapped up, pale ears jolted up like an alerted animal. For a second she looked up into the blue sunlight falling like water inside the dome, listening keenly, wondering if the pirates had returned. The young forest around her was quiet, holding its breath along with her. Then slowly, when nothing followedand quietness started to droop back into the dome and Ziv breathed out before she turned back to Cayne: “...I am just...probably just nervouse, no need to kriffing worry.”

In the shadow of a young tree with blue leafs that seemed to glow like sapphires in the azure sunlight was standing an old metalcontainer in which harvestmachines were transported. At the side was a electric pad in which the Tynnan swiftly entered a code so the door swung open with a creaking noise that hurted in the ears: “The cuddly flowers are good to be prepared as a healingsalve I already have some prepared, but I will show you how you can start your first batch yourself so you can do that on your own. Also this one is perfect as a ground-cover plant when you start to cultivate an area, its saving water in the soil and filtering poisons out of the ground to prepare the ground for bigger plants in some years. Also they only open their flowers when they do not catch any vibratons, so when you are bored you can sit between them and look how long you manage to sit without moving until they open their flowers. One of my teacher called that meditaive, I call it kriffing boring, but what-kriffing-ever.Yeh, I know years sound kriffing long but thats how terraforming and growing stuff works.”, years were probably for Ziv a lot of longer than for Cayne,not that the Tynnan knew that. Yet in the long days she spended alone on different plants with only the rustling of leafs in her ears and every other sentient life millions of miles away, those years felt especially long,especially lonely, especially silent: “Like This is only one of three biodomes I had set up at the same time on this planet and which between I am rotating regulary. When the atmosphere and growth becomes steady in them, I will widen the domes reach step by step by making them bigger and eventually close them together to one in which than settlers can live in.”

“Pass me the flowers, I will start to pluck off the petals and you get that white metal barrel from inside. Its closed, but you will still smell it before you see it. Also get me one of the pots with animalfat and one barrel with water for you to start with the flowers preperation. Then maybe you can tell me why you are so intrested in terraforming.” huffing quietly the Tynnan sat down on the red grass , grabbed inside her collar, pulled out a potato- peeler and without another word started to peel the silver skin of the fruit to collect the peel on her lap.

Caynes feet on the ground did not made any sound because he did not walked like someone with feet would walk, Ziv heard. Caynes scent and the pheromones were not read by Ziv on the others state of mind or physical health, because he did not used the pheromones that a body like his would usually emit, Ziv smelled.

Caynes movements did not left the vibrations in the Tynnans Vibrassea, as someone of their size would usually do, Ziv felt.

The Tynnan with the naturally horrible bad eyesight did not needed to see the others hand glitching into a tentacle and back to a humanoid illusion, to know that there was something very wrong about her visitor. She never trusted her eyes anyway. Also Ziv did not cared.

They were here to learn and Ziv was more than willing to help and support anyone who was willing to learn. Also Ziv liked to show her gardens.

Teaching and learning, especially about healingherbs and terraforming as topics to help people, was never bad, in fact, it was the most noble thing one could do as a teacher. So whatever or whoever her visitor was,was not important. Also Ziv loved teaching and Cayne was willing to be teached. 

Too overly dramatically to be serious in the slightest, Ziv placed a small paw on her chest and gasped theatralically from between sharp teeth: “That you say when honey is the best kriffing antiseptic you can find at any planet where there are some kind of bee-relative? The poor kriffing sugar, what a kriffing bad name you give it! How could you!” The Tynnan managed to keep up the dramatic facade for exactly one more second, before she wriggled her fluffy ears like a humanoid would wriggle their eyebrows, wildly enough to make her earpiercing plink. Carefully she turned around, holding the fruit in one of her small paws:

“I am joking, don´t worry.You are right, yeh, sugar is not exactly the best thing to put on a kriffing injury, but what we will use from this fruit is not the sweet fruitflesh, but the silver peel. What the tree does to keep insects away from the fruitflesh that is to support its seeds, are chemicals and enzyms that work poisonous for the insects on the trees homeplanet. But as it is often, its the amount of the Kriffey that makes the poison and in our case its poisonous enough to kill bacteria in an injury and keep it clean, but not poisonous enough to actually hurt me by entering my body through the open injury.I mean,I know I am a tiny kriffer and you are-” she looked up to Cayne, then down at them and tilted her head to the side with a smile that showed the sharp ends of her carnivorous teeth. The Tynnan did not said anything about the height of the others disguise, because in a dark part of her mind she knew it was a disguise like a small animal would instinctive know a coming but yet not seen stormwave would drown it and could never be survived or stopped by anything the small animal could ever do, but the humor was still in her voice: “...-Well. I and you are for sure bigger than the insects that bite on the trees homeplanet into the peel, so that poison is not enough to actually hurt us. The kriffing opposite, actually. Also, have you ever eaten the fruitflesh I mean, I have to look out for what I eat, so its kriffing sharp no for me because 90% of my diet is kriffing blood, bonemarrow and flesh, but when you are already here I could actually let the fruit be eaten and enjoyed instead of using the fruitflesh as compost.” Ziv turned around, cheeped quietly and held a free paw to her side where the sudden movement stabbed a flash of pain from a broken rip into her torso, before, taking deep breaths for a few seconds. she forced the pain down and continued on the narrow, beaten path. Although her voice sounded a little more flat than before and her movements were heavier: “Come along, pup. There is still another herb to get and then I show you how you can prepare those, yeh? Small steps and small beginnings and all that Kriffery. ”

[ @visceratorn​ ]

[jordankwalker]

Day 28 #stradaeasel challenge Behold, the beautiful solvent jar that I never use! I forget where I acquired this awesome container, but years ago I filled it with walnut oil back when that was a medium I liked to work with. Shortly thereafter, I decided that I didn't really like working with walnut oil after all, so since then the jar has served more of a decorative purpose in the studio rather than a utilitarian one. It was pretty fun to work out that metallic patina! #stilllifepainting #oilpainting #fineart #allaprima #artwork #artcollector #artforsale #pacificnorthwest #inyeriordesign #metalcontainer #solventjar #macrolichen #dailypainting #stradaeaselchallenge2021 @strada.easel https://www.instagram.com/p/CKnwTjdjJkM/?igshid=169eh3as6t580

[lelienhof]

Shadows and rust #rust #flakypaint #tuja #toll #green #yellow #photography #metalcontainer #container #lostplaces #fotografia #jungle #eldorado (ved Ammerudveien (Oslo)) https://www.instagram.com/p/CDspdL1gHPU/?igshid=vii4cfrewfp0

[cjreuse]

#Repost @sccpgh with @get_repost ・・・ Hope you had a wonderful weekend! This is a reminder that Wednesday will be the last day to sign up for this Saturday's (July 13) Tin Can Collage workshop with West Virginia artist Robert Villamagna (@wv_tinman ) Here is a regram of what Robert has been working on lately, it is always super cool to see the work in progress photos. We promise this will be a really fun and inspiring hands-on workshop! Robert is also a wonderful instructor and artist to learn from. You can sign up online (see link in profile) #handsonworkshop #art #artmaking #tincancollage #cccjpartnership #creativereuse #recyle #metalcontainers #transformation #artistled #workshop #artclass #RobertVillamagna https://www.instagram.com/p/BzqrbHyB05B/?igshid=168ojq5hqa0n

[mycyberattic]

Vintage Large Hammered Copper Wall Salt Box Container With Hinged Lid from the 70s, Www.mycyberattic.etsy.com, #saltbox #hammeredcopper #walldecorations #frenchcountrydecor #copper #metalcontainers #kitchenstorage #farmhousedecor #etsyfinds https://www.instagram.com/p/CiyPEjhvjoQ/?igshid=NGJjMDIxMWI=

[lupine-publishers-mams]

Groups 4 and 15 and Organotin Condensation Polymers for The Treatment of Cancers and Viruses| Lupine Publishers

Lupine Publishers| Material Science Journal

Abstract

This short review describes the use of group 4 metallocenes, group 15 organometallics and organotin polymers in the treatment of human cancer tumors and viruses. These metal-containing polymers show good inhibition of all the main group solid tumors including pancreatic, lung, brain, breast, prostate and colon human cell lines. They also show inhibition of a variety of viruses including zika, herpes and vaccinia viruses. Synthesis of the polymers is rapid employing interfacial polymerization and commercially available reactants. They offer physicians a new class of drugs for the treatment of a variety of cancers and viruses.

Keywords: Cancer; Viruses; Interfacial polymerization; Brain cancer; Pancreatic cancer; Zika virus; Vaccinia virus; Breast cancer; Herpes virus

Introduction

Use of metal-containing agents to treat various medical problems is well known [1-22]. Here the focus is on activities to supply metalcontaining polymers for the treatment of various cancers and viruses. While we have had extensive experience with platinum and palladium polymers for the treatment of a variety of cancers, the current emphasis is on polymers formed by incorporation of groups 4 and 15 metals and organotin condensation polymers for the treatment of cancers and viruses [23-41]. These two polymer types are different with their own separate biological characterizations [26]. For instance, the platinum and palladium polymers are addition products and not stable for long times in solution. By comparison, the groups 4 metallocene and organotin and group 15 polymers are condensation polymers and exhibit good stability to over 30 weeks in solution so can be treated differently with respect to biological and physical characterizations [26-41].

Synthesis

Synthesis occurs employing interfacial polymerization [42- 46]. It is a rapid polymerization system because high-energy reactants are employed. These high-energy reactants are acid halides. A typical condensation reaction has an activation energy of about 30-40Kcal/mol whereas the activation energy for the acid halide reactions is on the order of 20Kcal/mol. The interfacial polymerization is employed industrially to synthesize aromatic polyamides (nylons) and polycarbonates so industry is familiar with the system [47,48]. These interfacial polycondensation reactions form polymer within less than one minute in decent yield. For the syntheses described here, commercially available reactants are employed allowing ready reproduction and scale-up to ton levels in a somewhat straightforward manner. Rapid stirring is employed, generally about 18,000 rpm. This allows both the rapid polymerizations to occur with an increase in interfacial contact area of over ten thousand compared to non-stirred systems, and good reproducibility. For the systems described here, the reaction vessel is a simple glass reaction vessel, one-quart Kimax emulsifying jar, fitted onto a Waring Blender. To illustrate the overall reactions, products formed for the organotin polymers have a repeat unit described as follows.

R2SnX2+X-R-Y-> -(-SnR2-R-)-

where X and Y are normally Lewis bases such as alcohols, amines, acid salts, thiols, etc. These reaction sites are often varied for a single Lewis base such as an amino acid, shown below, that has both acid and amine reactant sites. Examples of overall reaction products for each of the three condensation polymer groups are given following. Reaction between the amino acid diglycine and dimethyltin dichloride is described (Figure 1). The polymer is described as a poly (amine ester) with the organotin unit considered an organic moiety such as a methylene unit in such naming. For the Group 4 metallocenes, the reaction employing titanocene dichloride as the Lewis acid, the repeat unit for a product formed from titanocene dichloride and chelidonic acid is given (Figure 2). Finally, for reactions involving group 15 metals, the repeat unit formed from reaction between triphenylantimony dichloride and 3,5-pyridinedicarboxylic acid forming a polyester is given (Figure 3). The metal is generally located in the Lewis acid portion while the non-metal reactant is the Lewis base. In certain cases, the Lewis base portion may also contain a metal, usually iron and cobalt. The iron is present as a ferrocene while the cobalt is present as a cobaltocene [32].

Figure 1: Synthesis of organotin poly (amine esters) from reaction of diglycine and dimethyltin dichloride where R represents simple chain extension.

Figure 2: Synthesis of polyesters from reaction with titanocene dichloride and chelidonic acid where R represents simple chain extension.

Cancer

It was initially mistakenly assumed that these metal-containing compounds inhibited cancer by the same mechanism as the platinum-containing drugs as cisplatin and other similar platinum containing drugs [26,50]. (The platinum-containing drugs currently are employed in over 60% of the chemo drug treatments generally as one of the components.) It is now known that this is not true so that they can be coupled with the drugs described here as co-drugs that will affect inhibition of cancer through two distinct avenues. The platinum-containing drugs are quite toxic resulting in the presence of many negative side effects [26]. Our effort is to create drugs that have similar or superior ability to inhibit cancer but without the unwanted side effects. All of the metal-containing drugs operate primarily on the DNA site for inhibition of the cancer cell lines [26,50].

The polymers synthesized by us have shown good ability to inhibit a variety of cancer cell lines Table 1. These cell lines represent all of the major human solid tumor cell lines. These cell lines include resistant cells meaning cell lines that have shown ability to resist treatment with the traditional anticancer drugs [39] (Table 1). Inhibition depends on the metal atom present as well as the nature of the Lewis base. With respect to the metal, in general, inhibition is of the order Hf=Zr>Ti>Sn>Sb, Bi, As. Inhibition is also dependent on the specific Lewis base. A primary measure of the ability for a drug to inhibit cancer growth is the effective concentration, EC. The 50% effective concentration, EC50, is the concentration of a toxicant, drug, or antibody that induces an inhibitory response halfway between the baseline and maximum after a specified exposure time. The desired outcome is to have low EC50 values as this indicates that only a small concentration of the anti-cancer agent is needed to elicit inhibition. For the compounds described here, once inhibition begins, the slope of the dose/concentration curve is high with inhibition being total. Depending on the specific Lewis acid/base the EC50 value is typically between milligrams/mL to nanograms/mL. The metal-containing compounds are often coupled with a Lewis base that exhibits some biological activity hoping for a syngeneic effect. Drugs that have been employed as the Lewis bases include ciprofloxacin, diethylstilbestrol, cephalexin, acyclovir, thiamine, dicumarol, camphoric acid, histamine, 2-ketoglutaric acid, salicylic acid, dipicolinic acid, isomanide, glycyrrhetinic acid, phentolamine, thiodiglycolic acid. Lewis bases that themselves exhibit no ability to inhibit cancer can also exhibit good inhibition when coupled with a metal-containing moiety. These include a wide variety of diols such as ethylene glycol, Figure 4 [29,50]. Recently, water-soluble drugs possessing the metal-containing unit were synthesized [29] employing as the Lewis base poly (ethylene glycol), PEG. The resulting water-soluble polymers exhibit good inhibition of the cell lines. Figure 5 contains the reaction between titanocene dichloride and PEG forming water soluble polyethers (Figures 4 & 5).

Figure 3: Synthesis of triphenylantimony polyesters from reaction with 3,5-pyridinedicarboxylic acid where R is simple chain extension.

Figure 4: Reaction between ethylene glycol and dibutyltin dichloride forming polyethers.

Figure 5: Formation of water-soluble polyethers from reaction of titanocene dichloride and various poly (ethylene oxides) where R represents simple chain extension.

Viruses

These metal-containing polymers also inhibit a variety of viruses including ones where no current drugs are available for treatment [40,41,49]. Table 2 contains viruses that have been inhibited by our metal-containing drugs including most recently the zika virus. These viruses include both DNA and RNA viruses. They include several that have been identified as possible weapons of mass destruction, namely the vaccinia virus. Three DNA viruses are effectively inhibited by the metal-containing polymers (Table 2). They are the vaccinia virus used to vaccinate humans against smallpox; herpes simplex virus 1, the virus responsible for over 45 million infections yearly in the US, comprising one of five adolescents and adults; and the varicella zoster virus, also a herpes virus and responsible for chickenpox and shingles. Thus, the metalcontaining polymers represent a possible potent approach towards inhibiting unwanted viruses (Table 2).

Table 1: Caner cell lines inhibited by metal-containing polymers described here.

From a cancer patient with ovarian cancer that had previously been treated with cytoxan, adriamycin, 5-fluorouracil, and Fur IV. From a cancer patient with ovarian cancer that had been treated with adriamycin, cyclophosphamide, and cisplatin.

Table 2: Viruses inhibited by metal-containing polymers discussed in this report.

Why Polymeric Drugs?

A critical question is “Why Polymeric Drugs?” What advantageousness do polymeric drugs offer [50-60]. Following briefly describes some advantages. Each of these advantages is related to the size of polymers and what such size offers. First, because of their size, polymers travel through the body, in particular the kidney and bladder, more slowly lessening organ damage allowing the organs to limit the negative effect [50,61]. Second, cancer cells are less cohesive, offering greater porosity, and are not as coherent as normal cells with relatively “rough” exteriors. This allows polymers to have a greater opportunity to be “snagged” by the cancer cells allowing them extended ability to be associated with the cancer cells resulting in a greater ability to inhibit cell growth. This scenario is described as the enhanced permeability and retention effect [50,62-64]. Third, increased size allows for a greater designing of the drug increasing its effectiveness [65-69]. This fine tuning includes attachment of “biological homing agents”. Thus, polymeric drugs offer advantageous over small molecule drugs that can be used to more effectively combat unwanted diseases compared to small molecule drugs.

Summary

Metal-containing polymers show ability to inhibit all the major solid tumor cancers as well as important viruses. They are easily synthesized and offer physicians new drugs to attack these harmful illnesses.

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[savege]

These plain Jane walls bout to get #Blasted with some #Paint #Color #ART #Graffiti and you already it’s Gonna Be #DOPE!!!! #SAVEGETV #IWIC #SAVEGE #Native #Indigenous #MetalContainer #DogOfInstagram

[woodlandrose]

Those eyes! #container #hunterdoncounty #metalcontainer #eyesonthings #photoart #photography #andrearosegrillo #farmlife (at Stockton, New Jersey)

[billionneuronscurious]

Artwork from Tin-Can.

[colorcanmetalpackaging]

New Arrival Round Shape Press To Open Airtight Metal Storage Box Small-Color Can The round tin box is different from other tin boxes, its opening way is special. You could open it when you press the certain place, this design makes the tin box more airtight. The size of this tin box is D75x20mm, you can use it to pack wax, lip balm, etc. Contact us to get more information. #roundtin #custombox #lipbalmbox #metalcontainer #tinbox #metalpackaging #waxbox #airtightbox You could learn more about us here: https://www.jhtin.com/ Email: noreen@jhtin.com Whatsapp: +86 18029106790

[cuucgardenplanters]

NEW SERIES!！！

STORAGE BOX - So much storage...

👀Visit more：www.cuucgardenplanters.com 🙌or contact Cola to get free samples：cola@cuuc-gardenplanters.com #Pot#GalvanizedPot#MetalFlowerPot#FlowerPot#GardenPot #foodstorage#container#bin#tinbox#lid#handle#pet#petfoodstorage#treat#TRENDY#dog#cat#storage#metalcontainer

[samdamp]

Experiment underway! We have a storage container for keeping the gear in and when we were moving stuff to our new bigger container it was noted there was a leak in this corner. Water pools on here and there had been an old repair that was rusting. Last year the hire company we bought it from did a patch repair on the top which is in grey and it got me thinking weather the waterproof DryFlex would do a job. So I cleaned up all the lose rust and paint with a brass scouring set. Once this was acceptable I put a coat of SBR onto the area to be patched. Once dry I mixed the DryFlex adhesive and applied it to the metal before ironing on a pre cut sheet of membrane. The area was left to cure before Drybase liquid membrane was applied (that’s the black). Now I’ll wait and monitor how the materials perform. It will give us some idea of the unknown quantities of this product as it’s not been tested on metal before. #experimental #theunknown #fingerscrossed #metalcontainerrepair #metalcontainers #drybase #dryflex #sbr #polymodifiedbinder #pushtheenvelope #homeimprovement #metalmickey #repair #patch #dampsam (at Barnsley)

[corbindallasmultipass]

Me whenever I see someone with plastic bags, disposable coffee cups, etcetera. Now more seriously as I believe positive recognition is more effective and helpful! Shutout to those using reusable items such as cotton bags, metal containers, old plastic containers that will last a life time if treated properly so they get maximum use! I see you 😘😍 Do the best you can, then do better. Be kind. #plasticbags #plastic #disposable #singleuse #coffeecups #positive #reusable #cottonbags #metalcontainers #plasticcontainers #reducereuserecycle #bekind